1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

Base Information

Chemical Name:1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester
CAS No.:135924-96-8
Molecular Formula:C₂₅H₃₆O₄Si
Molecular Weight:428.644
Hs Code.:

Synonyms:1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

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Chemical Property of 1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

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Technology Process of 1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

There total 1 articles about 1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78592-82-2
4-(tert-butyldimethylsilyloxy)-1-butyne

: 127020-54-6
3-Methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

: 135924-96-8
1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

Guidance literature:: Yield given. Multistep reaction;
DOI:10.1039/c39900001100

Reference yield:

: 135924-96-8
1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

: 1-[(E)-4-(tert-Butyl-dimethyl-silanyloxy)-but-1-enyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

Guidance literature:: With hydrogen; Lindlar's catalyst; In benzene; at 23 ℃; for 1h;
DOI:10.1039/c39900001100

Reference yield:

: 135924-96-8
1-[4-(tert-Butyl-dimethyl-silanyloxy)-but-1-ynyl]-3-methyl-2-oxo-cyclohexanecarboxylic acid benzyl ester

: 135924-86-6,135971-54-9
2-[(E)-4-(tert-Butyl-dimethyl-silanyloxy)-but-1-enyl]-6-methyl-cyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: H₂ / Lindlar catalyst / benzene / 1 h / 23 °C

2: W-2 Raney nickel, Et₃N / ethanol / 0.5 h / 23 °C

With W-2 Raney nickel; hydrogen; triethylamine; Lindlar's catalyst; In ethanol; benzene;
DOI:10.1039/c39900001100