methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

Base Information

Chemical Name:methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate
CAS No.:1606132-39-1
Molecular Formula:C₅₂H₆₂O₁₀Si
Molecular Weight:875.144
Hs Code.:

methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

Synonyms:methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

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Chemical Property of methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

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Technology Process of methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

There total 15 articles about methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 1606132-37-9
methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-hydroxyhex-2-en-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

: 824-94-2
p-methoxybenzyl chloride

: 1606132-39-1
methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

Guidance literature:: methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-hydroxyhex-2-en-1-yl)-2,2-dimethyl-1,3-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.5h;

p-methoxybenzyl chloride; With sodium iodide; In N,N-dimethyl-formamide; at 50 ℃; for 6h;

Reference yield:

: 1606132-34-6
C₂₁H₂₂O₈

: 1606132-39-1
methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium hydrogencarbonate / N,N-dimethyl-formamide / 6 h / 40 °C

2.1: N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 2 h / 0 - 20 °C

3.1: methanol; sodium tetrahydroborate / 4 h / 20 °C

4.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 3 h / 20 °C

5.1: n-butyllithium / tetrahydrofuran / 1.5 h / -78 °C

5.2: 2 h / -78 °C

6.1: hydrogen; quinoline; rosenmund catalyst / ethyl acetate / 8 h / 20 °C

7.1: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C

7.2: 6 h / 50 °C

With quinoline; methanol; sodium tetrahydroborate; n-butyllithium; rosenmund catalyst; hydrogen; sodium hydride; sodium hydrogencarbonate; potassium hydrogencarbonate; Dess-Martin periodane; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; dichloromethane; ethyl acetate; N,N-dimethyl-formamide;

Reference yield:

: 1606132-42-6
C₂₃H₂₆O₈

: 1606132-39-1
methyl 3'-((4R,5R)-5-((5R,Z)-5-((tert-butyldiphenylsilyl)oxy)-1-((4-methoxybenzyl)oxy)hex-2-en-1-yl)-2,2-dimethyl-1,4-dioxoran-4-yl)-5-methoxy-3-(methoxymethoxy)-[1,1'-biphenyl]-2-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran / 1.5 h / -78 °C

1.2: 2 h / -78 °C

2.1: hydrogen; quinoline; rosenmund catalyst / ethyl acetate / 8 h / 20 °C

3.1: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C

3.2: 6 h / 50 °C

With quinoline; n-butyllithium; rosenmund catalyst; hydrogen; sodium hydride; In tetrahydrofuran; ethyl acetate; N,N-dimethyl-formamide;