(Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Base Information

Chemical Name:(Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate
CAS No.:142532-25-0
Molecular Formula:C₂₁H₂₃NO₂
Molecular Weight:321.419
Hs Code.:

Synonyms:(Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Suppliers and Price of (Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

There total 5 articles about (Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 540-88-5
acetic acid tert-butyl ester

: 142532-20-5
7-Phenylbicyclo<4.2.0>octa-1,3,5-triene-7-carbonitrile

: 142532-25-0
(Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Guidance literature:: With magnesium bis(N,N-diisopropylamide); In tetrahydrofuran; diethyl ether; at 0 ℃; for 1.5h;

Reference yield:

: 3469-06-5
benzocyclobutenone

: 142532-25-0
(Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Mg / 1.) THF, 2.) -78 deg C, 30 min

2: 71 percent / BF₃*OEt₂ / CH₂Cl₂ / 25 h / 0 °C

3: 72 percent / magnesium bis(diisopropylamide) / diethyl ether; tetrahydrofuran / 1.5 h / 0 °C

With boron trifluoride diethyl etherate; magnesium; magnesium bis(N,N-diisopropylamide); In tetrahydrofuran; diethyl ether; dichloromethane;

Reference yield:

: 19164-61-5
7-phenylbicyclo<4.2.0>octa-1,3,5-trien-7-ol

: 142532-25-0
(Z)-1,1-Dimethylethyl 3-amino-3-(7'-phenylbicyclo<4.2.0>octa-1',3',5'-trien-7'-yl)propenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / BF₃*OEt₂ / CH₂Cl₂ / 25 h / 0 °C

2: 72 percent / magnesium bis(diisopropylamide) / diethyl ether; tetrahydrofuran / 1.5 h / 0 °C

With boron trifluoride diethyl etherate; magnesium bis(N,N-diisopropylamide); In tetrahydrofuran; diethyl ether; dichloromethane;