Diethylgalactarate

Base Information

• Chemical Name: Diethylgalactarate
• CAS No.: 15909-67-8
• Molecular Formula: C10H18 O8
• Molecular Weight: 266.248
• Hs Code.: 2918199090
• Mol file: 15909-67-8.mol

Synonyms:Galactaricacid, diethyl ester (7CI,8CI,9CI); Mucic acid, diethyl ester (6CI); Diethylgalactarate; Diethyl mucate

Chemical Property of Diethylgalactarate

Chemical Property:

• PSA: 133.52000
• LogP: -2.44380

Purity/Quality:

98% ^*data from raw suppliers

DIETHYLGALACTARATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diethylgalactarate

There total 3 articles about Diethylgalactarate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

ethanol (64-17-5) + meso-galactaric acid (526-99-8,1213827-87-2,7231-46-1) → (2R,3S,4R,5S)-2,3,4,5-Tetrahydroxy-hexanedioic acid diethyl ester (15909-67-8)

Guidance literature:

With sulfuric acid; for 24h; Reflux;

DOI:10.1002/anie.201310991

Reference yield:

ethanol (64-17-5) + mucic acid azide → carbamoyl azide (13125-56-9) + hexahydro-furo[2,3-d;5,4-d']bis-oxazole-2,6-dione (861372-92-1) + (2R,3S,4R,5S)-2,3,4,5-Tetrahydroxy-hexanedioic acid diethyl ester (15909-67-8) + butane-2,3-diol-1,4-dial (34361-91-6)

Guidance literature:

aehnlich verlauft die Einw_. von Methanol und von Wasser;

Reference yield:

ethanol (64-17-5) → (2R,3S,4R,5S)-2,3,4,5-Tetrahydroxy-hexanedioic acid diethyl ester (15909-67-8)

Guidance literature:

With hydrogenchloride; zuletzt vorsichtige Zersetzung mit Wasser;

upstream raw materials:

ethanol

meso-galactaric acid

Downstream raw materials:

galactaric acid dianilide

pyrrole-2-carboxamide

1,3,4,6-Tetra-O-acetyl-2,5-di-O-tosylgalactitol

D-galactitol

Refernces

• 1、 Morgan,Wolfrom. "-". . p. 1897. Retrieved 1956.
• 2、 -. "ELASTOMER COMPOSITIONS COMPRISING AN ADDUCT BETWEEN AN SP2 HYBRIDIZED CARBON ALLOTROPE AND A DICARBOXYLIC ACID DERIVATIVE". Page/Page column 43-44. . Retrieved 2020/11/12.
• 3、 Li, Xiukai,Wu, Di,Lu, Ting,Yi, Guangshun,Su, Haibin,Zhang, Yugen. "Highly efficient chemical process to convert mucic acid into adipic acid and DFT studies of the mechanism of the rhenium-catalyzed deoxydehydration". supporting information. p. 4200 - 4204. Retrieved 2014/05/06.