[Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

Base Information

Chemical Name:[Pt(SH)2(1,3-bis(diphenylphosphino)propane)]
CAS No.:637032-74-7
Molecular Formula:C₂₇H₂₈P₂PtS₂
Molecular Weight:673.679
Hs Code.:

Synonyms:[Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

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Chemical Property of [Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

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Technology Process of [Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

There total 1 articles about [Pt(SH)2(1,3-bis(diphenylphosphino)propane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 59329-00-9
[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

: 7783-06-4
hydrogen sulfide

: 7440-23-5
sodium

: 637032-74-7
[Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

Guidance literature:: In ethanol; Na was dissolved in EtOH, exposed to H2S (1 atm) for 1 h, Pt-complex wasadded, stirred for 24 h under H2S; filtered, washed with water, EtOH, ether;
DOI:10.1016/S0020-1693(03)00211-1

Reference yield: 83.0%

: 120311-09-3
(η(5)-C5Me5)Mo(NO)Cl2

: 637032-74-7
[Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

: [(1,3-bis(diphenylphosphino)propane)Pt(μ-S)2Mo(NO)(η5-C5Me5)]

Guidance literature:: With triethylamine; In tetrahydrofuran; under N2 atm. to suspn. Pt complex in THF at -60°C Mo complex in THF and Et3N were added, warmed to room. temp. and stirred overnight; react. mixt. was dried in vacuo, residue was dissolved in CH2Cl2 and chromd. on alumina column (CH2Cl2), soln. was evapd., residue was recrystd.from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/ic702309h

Reference yield: 81.0%

: 1-pyridyl-2-yl-2-bromoethanone

: 637032-74-7
[Pt(SH)2(1,3-bis(diphenylphosphino)propane)]

: 637032-76-9
Pt(diphenyldiphosphinopropane)(C₂S₂(2-pyridine)(H))

Guidance literature:: In N,N-dimethyl-formamide; ligand was added to DMF soln. of Pt-complex, stirred for 2 h under N2; solvent was removed in vacuo, alumina column chromy. with CH2Cl2, evapd.to dryness;
DOI:10.1016/S0020-1693(03)00211-1