N-BUTYLHEXAMETHYLENEIMINE 97

Base Information

• Chemical Name: N-BUTYLHEXAMETHYLENEIMINE 97
• CAS No.: 15753-35-2
• Molecular Formula: C10H21N
• Molecular Weight: 155.283
• Hs Code.: 2933990090
• Mol file: 15753-35-2.mol

Synonyms:Hexamethylenimine,1-butyl- (6CI);1-Butylhexahydro-1H-azepine;NSC 96846;1-Butylazepane;N-Butylhexamethyleneimine;

Chemical Property of N-BUTYLHEXAMETHYLENEIMINE 97

Chemical Property:

• Vapor Pressure: 0.371mmHg at 25°C
• Refractive Index: n20/D 1.456
• Boiling Point: 197.8 °C at 760 mmHg
• Flash Point: 78.1 °C
• PSA: 3.24000
• Density: 0.835 g/cm³
• LogP: 2.60040

Purity/Quality:

98%Min ^*data from raw suppliers

N-Butylhexamethyleneimine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-BUTYLHEXAMETHYLENEIMINE 97

There total 9 articles about N-BUTYLHEXAMETHYLENEIMINE 97 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.8%

hexamethylene imine (111-49-9) + butyraldehyde (123-72-8) → 1-N-butylhexamethyleneimine (15753-35-2)

Guidance literature:

With nickel; hydrogen; In neat (no solvent); at 180 ℃; under 760.051 Torr; Flow reactor;

DOI:10.1134/S1070363219120016

Reference yield: 77.4%

N-butylhexamethyleneiminium bromide → 1-N-butylhexamethyleneimine (15753-35-2)

Guidance literature:

With sodium carbonate; In water; at 20 ℃; for 1h;

DOI:10.1039/c5sc03019f

Reference yield: 64.3%

hexamethylene imine (111-49-9) + 1-bromo-butane (109-65-9) → 1-N-butylhexamethyleneimine (15753-35-2)

Guidance literature:

With potassium carbonate; In methanol; at 20 ℃; for 24h; Cooling with ice;

upstream raw materials:

hexamethylene imine

1-bromo-butane

6-n-butylamino-1-hexanol

1-<(butyl(5-hexenyl)carbamoyl)oxy>-2(1H)-pyridinethione

Refernces

• 1、 Martínez-Franco, Raquel,Paris, Cecilia,Martínez-Armero, Marta E.,Martínez, Cristina,Moliner, Manuel,Corma, Avelino. "High-silica nanocrystalline Beta zeolites: Efficient synthesis and catalytic application". . p. 102 - 108. Retrieved 2015.
• 2、 Neale, Alex R.,Murphy, Sinead,Goodrich, Peter,Hardacre, Christopher,Jacquemin, Johan. "Thermophysical and Electrochemical Properties of Ethereal Functionalised Cyclic Alkylammonium-based Ionic Liquids as Potential Electrolytes for Electrochemical Applications". . p. 2040 - 2057. Retrieved 2017.
• 3、 Gallego, Eva M.,Paris, Cecilia,Díaz-Rey, M. Rocío,Martínez-Armero, Marta E.,Martínez-Triguero, Joaquín,Martínez, Cristina,Moliner, Manuel,Corma, Avelino. "Simple organic structure directing agents for synthesizing nanocrystalline zeolites". . p. 8138 - 8149. Retrieved 2017/11/27.