Hexyldimethylphosphine oxide

Base Information

• Chemical Name: Hexyldimethylphosphine oxide
• CAS No.: 28520-49-2
• Molecular Formula: C₈H₁₉OP
• Molecular Weight: 162.212
• Hs Code.: 2931900090
• UNII: 76AH0OCX89
• DSSTox Substance ID: DTXSID30405524
• Nikkaji Number: J1.105.908B
• Wikidata: Q27266477
• Mol file: 28520-49-2.mol

Synonyms:Hexyldimethylphosphine oxide;Dimethylhexylphosphine oxide;28520-49-2;1-dimethylphosphorylhexane;N-Hexyldimethyl phosphine oxide;Phosphine oxide, hexyldimethyl-;UNII-76AH0OCX89;76AH0OCX89;dimethyl-hexylphosphine oxide;SCHEMBL1725369;DTXSID30405524;AKOS006275552;Hexyl(dimethyl)oxo-lambda~5~-phosphane;Q27266477

Chemical Property of Hexyldimethylphosphine oxide

Chemical Property:

• Vapor Pressure: 0.00785mmHg at 25°C
• Boiling Point: 276.9°Cat760mmHg
• Flash Point: 121.3°C
• PSA: 26.88000
• Density: 0.878g/cm³
• LogP: 3.18940
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 162.117352223
• Heavy Atom Count: 10
• Complexity: 114

Purity/Quality:

99% ^*data from raw suppliers

1-(DIMETHYLPHOSPHORYL)HEXANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCP(=O)(C)C

Technology Process of Hexyldimethylphosphine oxide

There total 3 articles about Hexyldimethylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-hexene (592-41-6,25067-06-5) + dimethyl phosphine oxide (7211-39-4) → Hexyl-dimethyl-phosphinoxid (28520-49-2)

Guidance literature:

With di-tert-butyl peroxide; at 150 - 170 ℃;

Reference yield:

Hexyl-phosphonsaeure-dimethylester (6172-92-5) + methylmagnesium bromide (75-16-1) → Hexyl-dimethyl-phosphinoxid (28520-49-2)

Guidance literature:

With sodium triflate; In tetrahydrofuran; for 2h; Inert atmosphere; Reflux;

DOI:10.1021/om500854u

Reference yield:

→ Hexyl-dimethyl-phosphinoxid (28520-49-2)

Guidance literature:

Dimethylphosphinoxid;

upstream raw materials:

1-hexene

dimethyl phosphine oxide

Hexyl-phosphonsaeure-dimethylester

methylmagnesium bromide

Refernces