(1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

Base Information

Chemical Name:(1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol
CAS No.:224442-21-1
Molecular Formula:C₃₂H₄₀O₂Si
Molecular Weight:484.754
Hs Code.:

Synonyms:(1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

Suppliers and Price of (1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

Chemical Property:

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Technology Process of (1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

There total 1 articles about (1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: (7R,3Z,8E)1-phenyldeca-3,8-diene-1,7-diol

: 224442-21-1
(1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

: (1R,7R,3Z,8E)-1,7-bis(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-diene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 16h;
DOI:10.1016/S0040-4020(98)01179-X

Reference yield: 76.0%

: 224442-21-1
(1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

: 62-23-7
4-nitro-benzoic acid

: 224442-22-2
(1S,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-(4-nitrobenzoyloxy)-1-phenyldeca-3,8-diene

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In toluene; at -35 ℃; for 2h;
DOI:10.1016/S0040-4020(98)01179-X

Reference yield:

: 224442-21-1
(1R,7R,3Z,8E)-7-(tert-butyldiphenylsilyloxy)-1-phenyldeca-3,8-dien-1-ol

: (1S,7R,3Z,8E)1-phenyldeca-3,8-diene-1,7-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / diethyl azodicarboxylate, PPh₃ / toluene / 2 h / -35 °C

2: 45 percent / NaOH / methanol / 1 h

3: 90 percent / TBAF / tetrahydrofuran / 16 h

With sodium hydroxide; tetrabutyl ammonium fluoride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; toluene;
DOI:10.1016/S0040-4020(98)01179-X