(3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene

Base Information

Chemical Name:(3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene
CAS No.:133728-52-6
Molecular Formula:C₂₆H₃₆OS
Molecular Weight:396.637
Hs Code.:

Synonyms:(3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene

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Chemical Property of (3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene

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Technology Process of (3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene

There total 2 articles about (3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 87745-21-9,130274-08-7,130322-24-6
(3aR*,4aR*,5R*,6R*,8aS*)-2,3a,4,4a,5,7,8,8a,9,10-decahydro-3a,8a-dimethyl-5-methylene-1-isopropylbenzazulen-6(3H)-ol

: 931-59-9
benzenesulfenyl chloride

: 133728-52-6
(3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene

Guidance literature:: With TEA; In diethyl ether; for 12h; Ambient temperature;
DOI:10.1021/jo00012a035

Reference yield:

: 133728-51-5
(3aR*,4aR*,5R*,6R*,8aS*)-3,3a,4,4a,5,7,8,8a,9,10-decahydro-3a,8a-dimethyl-5-<(tosyloxy)methyl>-1-isopropylbenzazulen-6(2H)-ol

: 133728-52-6
(3aR,4aS,8aS)-5-Benzenesulfinylmethyl-1-isopropyl-3a,8a-dimethyl-2,3,3a,4,4a,7,8,8a,9,10-decahydro-benzo[f]azulene

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / KOAc / dimethylformamide / 21 h / 65 °C

2: 98 percent / TEA / diethyl ether / 12 h / Ambient temperature

With TEA; potassium acetate; In diethyl ether; N,N-dimethyl-formamide;
DOI:10.1021/jo00012a035