1-benzyl-4-methylene azepane

Base Information

Chemical Name:1-benzyl-4-methylene azepane
CAS No.:109105-87-5
Molecular Formula:C₁₄H₁₉N
Molecular Weight:201.312
Hs Code.:

Synonyms:1-benzyl-4-methylene azepane

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Chemical Property of 1-benzyl-4-methylene azepane

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Technology Process of 1-benzyl-4-methylene azepane

There total 5 articles about 1-benzyl-4-methylene azepane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 109105-84-2
Benzyl-(4-trimethylsilanylmethyl-pent-4-enyl)-amine

: 109105-87-5
1-benzyl-4-methylene azepane

Guidance literature:: With trifluoroacetic acid; In tetrahydrofuran; water; for 42h;
DOI:10.1016/S0040-4039(00)85134-5

Reference yield: 62.0%

: 153894-91-8
Benzyl-trimethylsilanylmethyl-(4-trimethylsilanylmethyl-pent-4-enyl)-amine

: 109105-87-5
1-benzyl-4-methylene azepane

Guidance literature:: With tetrabutylammonium hexanitratocerate(IV); In acetonitrile; at 25 ℃; for 4h;
DOI:10.1021/jo971706n

Reference yield:

: 99667-09-1
4-((trimethylsilyl)methyl)pent-4-en-1-ol

: 109105-87-5
1-benzyl-4-methylene azepane

Guidance literature:: Multi-step reaction with 4 steps

1: n-BuLi / tetrahydrofuran / 3 h / 25 °C

2: acetonitrile / 3 h / Heating

3: 71 percent / K₂CO₃ / acetonitrile / 12 h / Heating

4: 62 percent / (n-Bu₄N)2Ce(NO₃)6 / acetonitrile / 4 h / 25 °C

With n-butyllithium; tetrabutylammonium hexanitratocerate(IV); potassium carbonate; In tetrahydrofuran; acetonitrile;
DOI:10.1021/jo971706n