4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Base Information

Chemical Name:4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)
CAS No.:1383124-71-7
Molecular Formula:C₄₈H₃₇N₅O₆S₂
Molecular Weight:843.984
Hs Code.:

4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Synonyms:4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Suppliers and Price of 4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

There total 6 articles about 4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1383124-67-1
5,5’-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-2-carbaldehyde)

: 119-18-6
5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid

: 1383124-71-7
4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Guidance literature:: With ammonium acetate; In acetic acid; at 110 ℃; for 4h; Inert atmosphere;
DOI:10.1080/15421406.2011.601189

Reference yield:

: 4041-21-8
N-hexylcarbazole

: 1383124-71-7
4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Guidance literature:: Multi-step reaction with 4 steps

1: bromine / dichloromethane / 12 h / 20 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 20 - 65 °C / Inert atmosphere

3: trichlorophosphate / 1,2-dichloro-ethane / 8 h / 0 °C / Reflux

4: ammonium acetate / acetic acid / 4 h / 110 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium acetate; bromine; trichlorophosphate; In tetrahydrofuran; dichloromethane; acetic acid; 1,2-dichloro-ethane;
DOI:10.1080/15421406.2011.601189

Reference yield:

: 150623-72-6
3,6-dibromo-9-hexyl-9H-carbazole

: 1383124-71-7
4,4'-(5,5'-(9-hexyl-9H-carbazole-3,6-diyl)bis(thiophene-5,2-diyl))bis(methan-1-yl-1-ylidene)bis(5-oxo-1-phenyl-4,5-dihydro-1H-pyrazole-3-carboxylic acid)

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 20 - 65 °C / Inert atmosphere

2: trichlorophosphate / 1,2-dichloro-ethane / 8 h / 0 °C / Reflux

3: ammonium acetate / acetic acid / 4 h / 110 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; ammonium acetate; trichlorophosphate; In tetrahydrofuran; acetic acid; 1,2-dichloro-ethane;
DOI:10.1080/15421406.2011.601189