(RS)-(3-methyl-1-nitrobutan-2-yl)benzene

Base Information

Chemical Name:(RS)-(3-methyl-1-nitrobutan-2-yl)benzene
CAS No.:7796-81-8
Molecular Formula:C₁₁H₁₅NO₂
Molecular Weight:193.246
Hs Code.:

Synonyms:(RS)-(3-methyl-1-nitrobutan-2-yl)benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (RS)-(3-methyl-1-nitrobutan-2-yl)benzene

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Technology Process of (RS)-(3-methyl-1-nitrobutan-2-yl)benzene

There total 8 articles about (RS)-(3-methyl-1-nitrobutan-2-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 102-96-5
(2-nitroethenyl)benzene

: 625-81-0
diisopropyl zinc

: 7796-81-8
(RS)-(3-methyl-1-nitrobutan-2-yl)benzene

Guidance literature:: diisopropyl zinc; With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(l) iodide; (S)-1-(2-isobutyramido-3-methylbutyl)-3-(pyridin-2-yl)-1H-imidazol-3-ium chloride; In hexane; toluene; at 0 ℃; for 0.55h; Inert atmosphere;

(2-nitroethenyl)benzene; In hexane; toluene; at 0 - 20 ℃; for 24h; enantioselective reaction; Inert atmosphere;
DOI:10.1016/j.tet.2018.07.030

Reference yield:

: 851343-56-1
(E)-(3-methyl-1-nitrobut-1-en-2-yl)benzene

: 7796-81-8
(RS)-(3-methyl-1-nitrobutan-2-yl)benzene

Guidance literature:: With sodium tetrahydroborate; In tetrahydrofuran; methanol; at 20 ℃; Inert atmosphere;
DOI:10.1021/ja403777k

Reference yield:

: 611-70-1
phenyl isopropyl ketone

: 7796-81-8
(RS)-(3-methyl-1-nitrobutan-2-yl)benzene

Guidance literature:: Multi-step reaction with 4 steps

1: potassium tert-butylate / tetrahydrofuran

2: nitric acid / water

3: sodium hydroxide / water; dichloromethane

4: D-glucose; ene reductases from the old yellow enzyme-3; nicotinamide adenine dinucleotide phosphate; glucose dehydrogenase / dimethyl sulfoxide; aq. phosphate buffer / 24 h / 30 °C / pH 7 / Enzymatic reaction

With glucose dehydrogenase; D-glucose; ene reductases from the old yellow enzyme-3; potassium tert-butylate; nitric acid; nicotinamide adenine dinucleotide phosphate; sodium hydroxide; In tetrahydrofuran; aq. phosphate buffer; dichloromethane; water; dimethyl sulfoxide; 1: |Wittig Olefination;
DOI:10.1002/cctc.201500958