TRIS(ETHYLENEDIAMINE)COBALT(III) CHLORIDE TRIHYDRATE

Base Information

• Chemical Name: TRIS(ETHYLENEDIAMINE)COBALT(III) CHLORIDE TRIHYDRATE
• CAS No.: 14883-80-8
• Molecular Formula: C₆H₂₄CoN₆*3Cl*H₂O
• Molecular Weight: 363.664
• Mol file: 14883-80-8.mol

Synonyms:Cobalt(3+),tris(1,2-ethanediamine-N,N')-, trichloride, trihydrate, (OC-6-11)-; Cobalt(3+),tris(ethylenediamine)-, trichloride, trihydrate (8CI)

Chemical Property of TRIS(ETHYLENEDIAMINE)COBALT(III) CHLORIDE TRIHYDRATE

Chemical Property:

• Melting Point: decomposes at 275℃ [ALD94]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 183.81000
• Density: g/cm³
• LogP: -8.26770
• Water Solubility.: very soluble H2O [KIR79]

Purity/Quality:

98%Min ^*data from raw suppliers

Tris(ethylenediamine)cobalt (III) chloride trihydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(ETHYLENEDIAMINE)COBALT(III) CHLORIDE TRIHYDRATE

There total 16 articles about TRIS(ETHYLENEDIAMINE)COBALT(III) CHLORIDE TRIHYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

water (7732-18-5) + 1,2-diaminoethane dihydrochloride (333-18-6) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → [Co(ethylenediamine)3]Cl3·3H2O (207802-43-5,14883-80-8)

Guidance literature:

water; 1,2-diaminoethane dihydrochloride; cobalt(II) chloride; With sodium hydroxide; for 0.333333h; Sonication;

With dihydrogen peroxide; for 1.16667h; Sonication;

DOI:10.1016/j.ultsonch.2016.10.005

Reference yield: 30.0%

hydrogenchloride (7647-01-0,15364-23-5) + cobalt(II) chloride hexahydrate + water (7732-18-5) + ethylenediamine (107-15-3,85404-18-8) → tris(ethylenediamine)cobalt(III) chloride trihydrate (207802-43-5,14883-80-8)

Guidance literature:

With dihydrogen peroxide; Heating;

DOI:10.1039/d0dt01391a

Reference yield:

2{Co(en)3}Cl3*CoCl2*4H2O → tris(ethylenediamine)cobalt(III) chloride trihydrate (207802-43-5,14883-80-8) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1)

Guidance literature:

With water;

upstream raw materials:

d-{Coen3}Cl3*H2O

Δ-{Co(1,2-diaminoethane)3}I3

chloride

trans-dichlorobis(ethylenediamine)cobalt(III) chloride

Downstream raw materials:

[cis-Co(ethylenediamine)2Cl₂]Cl

Refernces

• 1、 Bala, Ritu,Behal, Jagriti,Kaur, Varinder,Jain, Subheet Kumar,Rani, Riveka,Manhas, Rajesh Kumari,Prakash, Vinit. "Sonochemical synthesis, characterization, antimicrobial activity and textile dyeing behavior of nano-sized cobalt(III) complexes". . p. 294 - 303. Retrieved 2017.
• 2、 Campanella, Anthony J.,Ozvat, Tyler M.,Rappé, Anthony K.,Sterbinsky, George E.,Zadrozny, Joseph M.. "EXAFS investigations of temperature-dependent structure in cobalt-59 molecular NMR thermometers". supporting information. p. 16380 - 16385. Retrieved 2020/12/03.