(2,2'-Bipyridine)dichloropalladium(II)

Base Information

• Chemical Name: (2,2'-Bipyridine)dichloropalladium(II)
• CAS No.: 14871-92-2
• Molecular Formula: C10H8 Cl2 N2 Pd
• Molecular Weight: 333.513
• European Community (EC) Number: 624-044-0
• Mol file: 14871-92-2.mol

Synonyms:14871-92-2;(2,2'-Bipyridine)dichloropalladium(II);(2,2 inverted exclamation marka-Bipyridine)dichloropalladium(II);dichloropalladium;2-pyridin-2-ylpyridine;SCHEMBL310576;AKOS024258162;AM84940;dichloro(2,2'-bipyridyl)palladium(ii);SC10510;2,2'-Bipyridine-dichloropalladium (1:1);DICHLORO(2,2'-BIPYRIDINE)PALLADIUM;FT-0697715;FT-0697716;F10004;(2,2invertedexclamationmarka-Bipyridine)dichloropalladium(II);Palladium, (2,2'-bipyridine-kappaN1,kappaN1')dichloro-, (SP-4-2)-

Chemical Property of (2,2'-Bipyridine)dichloropalladium(II)

Chemical Property:

• Boiling Point: 272.5oC at 760 mmHg
• Flash Point: 107.2oC
• PSA: 25.78000
• LogP: -3.84840
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 331.90993
• Heavy Atom Count: 15
• Complexity: 123

Purity/Quality:

≥99% ^*data from raw suppliers

(2,2′-Bipyridine)dichloropalladium(II) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.Cl[Pd]Cl

Technology Process of (2,2'-Bipyridine)dichloropalladium(II)

There total 34 articles about (2,2'-Bipyridine)dichloropalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

[2,2]bipyridinyl (366-18-7) + palladium dichloride → dichloro(2,2'-bipyridine)palladium(II) (14871-92-2)

Guidance literature:

With 1-butyl-3-methylimidazolium chloride; In chloroform-d1; at 20 ℃; for 2h; Time; Reagent/catalyst; Sonication;

DOI:10.1002/jccs.201200408

Reference yield: 98.0%

[2,2]bipyridinyl (366-18-7) + sodium tetrachloropalladate(II) → dichloro(2,2'-bipyridine)palladium(II) (14871-92-2)

Guidance literature:

In methanol; byproducts: NaCl; under N2; ligand (1.09 equiv.) added to soln. of Pd complex in MeOH; stirred at room temp. for 1 h; filtered; ppt. washed with water, EtOH and Et2O; elem. anal.;

DOI:10.1016/j.jorganchem.2004.01.032

Reference yield: 97.0%

PdCl2(P(C6H5)(C5H4N)2)2 (110173-82-5,110222-28-1) → dichloro(2,2'-bipyridine)palladium(II) (14871-92-2)

Guidance literature:

With NaCl; In ethanol; warming soln. of PdCl2(PC6H5(C5H4N)2)2 and satd. aq. NaCl in 95 % ethanol at 50-60°C for 18 h, concentration in vac.;; dissolving in CH2Cl2, filtration, concentration;;

upstream raw materials:

[2,2]bipyridinyl

palladium

bis(benzonitrile)palladium(II) dichloride

potassium tetrachloropalladate(II)

Downstream raw materials:

Pd(O₂CC₆H₄CF₃)2(2,2'-bipyridine)

Pd((C₅H₄N)2)(C₆H₅C(O)NCH(CH(CH₃)2)COO)

C₂₃H₂₅N₃O₄PdS

[Pd(CH(COMe)C(O)NPh)(2,2-bipyridyl)]