Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

Base Information

Chemical Name:Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol
CAS No.:141240-12-2
Molecular Formula:C₂₅H₃₂Cl₂O₄Si
Molecular Weight:495.518
Hs Code.:

Synonyms:Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

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Technology Process of Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

There total 3 articles about Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.4%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 141240-06-4,141317-10-4,144491-58-7
(Z)-2,4-O-benzylidene-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

: 141240-12-2
Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 0.75h; Ambient temperature;
DOI:10.1016/S0008-6215(00)90499-3

Reference yield:

: 141240-15-5
(Z)-2,4-O-Benzylidene-1-O-tert-butyldimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-3-O-(4-nitrobenzoyl)-D-xylo-hex-5-enitol

: 141240-12-2
Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / 1M H₂SO₄ / methanol / 0.75 h

2: 89.4 percent / imidazole / dimethylformamide / 0.75 h / Ambient temperature

With 1H-imidazole; sulfuric acid; In methanol; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(00)90499-3

Reference yield:

: 141240-05-3,141317-09-1
(Z)-1,3-di-O-acetyl-2,4-O-benzylidene-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

: 141240-12-2
Z-2,4-O-Benzylidene-1-O-tert-butyl-dimethylsilyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-xylo-hex-5-enitol

Guidance literature:: Multi-step reaction with 2 steps

1: 91.2 percent / 4M NaOCH₃ / CHCl₃; methanol / 0.5 h

2: 89.4 percent / imidazole / dimethylformamide / 0.75 h / Ambient temperature

With 1H-imidazole; sodium methylate; In methanol; chloroform; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(00)90499-3