4-carboxyphenyl boronic acid MIDA ester

Base Information

• Chemical Name: 4-carboxyphenyl boronic acid MIDA ester
• CAS No.: 1072960-67-8
• Molecular Formula: C₁₂H₁₂BNO₆
• Molecular Weight: 277.041
• Hs Code.: 2934999090
• Mol file: 1072960-67-8.mol

Synonyms:4-carboxyphenyl boronic acid MIDA ester

Chemical Property of 4-carboxyphenyl boronic acid MIDA ester

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

4-(6-Methyl-4,8-dioxo-1,3,6,2-dioxazaborocan-2-yl)benzoicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-carboxyphenyl boronic acid MIDA ester

There total 2 articles about 4-carboxyphenyl boronic acid MIDA ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-(hydroxymethyl)phenylboronic acid MIDA ester (1072960-82-7) + isopropyl alcohol (67-63-0,8013-70-5) → 4-carboxyphenyl boronic acid MIDA ester (1072960-67-8)

Guidance literature:

With Jones reagent; In acetone; at 0 - 23 ℃; Inert atmosphere;

DOI:10.1021/ja8063759

Reference yield: 90.0%

4-(hydroxymethyl)phenylboronic acid MIDA ester (1072960-82-7) + sulfuric acid (7664-93-9) → 4-carboxyphenyl boronic acid MIDA ester (1072960-67-8)

Guidance literature:

With chromium(VI) oxide; In acetone; CrO3, H2SO4, acetone, 23°C, 30 min;

DOI:10.1021/ja8063759

Reference yield: 89.0%

4-carboxyphenyl boronic acid MIDA ester (1072960-67-8) → 4-carboxyphenylboronic acid (14047-29-1)

Guidance literature:

With sodium hydroxide; water; In tetrahydrofuran; at 23 ℃; for 0.166667h; Inert atmosphere;

DOI:10.1021/ja8063759

upstream raw materials:

4-(hydroxymethyl)phenylboronic acid MIDA ester

sulfuric acid

isopropyl alcohol

Downstream raw materials:

4-carboxyphenylboronic acid