(5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

Base Information

Chemical Name:(5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol
CAS No.:441352-39-2
Molecular Formula:C₂₃H₃₂O₅
Molecular Weight:388.504
Hs Code.:

Synonyms:(5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

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Chemical Property of (5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

Chemical Property:

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Technology Process of (5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

There total 10 articles about (5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: ((5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptyloxy)-triisopropyl-silane

: 441352-39-2
(5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/S0040-4020(02)00045-5

Reference yield:

: 22900-10-3,35536-75-5,36792-85-5,113890-34-9,113890-37-2,133813-23-7
2-deoxy-D-ribose

: 441352-39-2
(5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

Guidance literature:: Multi-step reaction with 9 steps

1.1: tetrahydrofuran / 3 h / Heating

2.1: H₂ / 10 percent Pd/C / ethyl acetate; methanol / 20 °C

3.1: 16.33 g / camphorsulfonic acid / CH₂Cl₂ / 20 °C

4.1: i-Pr₂NEt; tetra-n-butylammonium iodide / CH₂Cl₂ / 72 h / 20 °C

5.1: LiAlH₄ / tetrahydrofuran / 0.75 h / 0 °C

6.1: 20.42 g / 2,6-lutidine / CH₂Cl₂ / 4 h / 0 - 20 °C

7.1: H₂ / 20 percent Pd/C / ethyl acetate; methanol / 20 °C

8.1: NaH / dimethylformamide / 0.5 h / 20 °C

8.2: tetra-n-butylammonium iodide / dimethylformamide / 20 °C

9.1: 14.03 g / tetra-n-butylammonium fluoride / tetrahydrofuran / 20 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; hydrogen; tetra-(n-butyl)ammonium iodide; sodium hydride; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00045-5

Reference yield:

: 116237-17-3
4-((2R,4S,5R)-5-Hydroxy-2-phenyl-[1,3]dioxan-4-yl)-butyric acid methyl ester

: 441352-39-2
(5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1.1: i-Pr₂NEt; tetra-n-butylammonium iodide / CH₂Cl₂ / 72 h / 20 °C

2.1: LiAlH₄ / tetrahydrofuran / 0.75 h / 0 °C

3.1: 20.42 g / 2,6-lutidine / CH₂Cl₂ / 4 h / 0 - 20 °C

4.1: H₂ / 20 percent Pd/C / ethyl acetate; methanol / 20 °C

5.1: NaH / dimethylformamide / 0.5 h / 20 °C

5.2: tetra-n-butylammonium iodide / dimethylformamide / 20 °C

6.1: 14.03 g / tetra-n-butylammonium fluoride / tetrahydrofuran / 20 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; tetrabutyl ammonium fluoride; hydrogen; tetra-(n-butyl)ammonium iodide; sodium hydride; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00045-5