bis(2-ethylphenyl) sulfide

Base Information

• Chemical Name: bis(2-ethylphenyl) sulfide
• CAS No.: 27560-62-9
• Molecular Formula: C₁₆H₁₈S
• Molecular Weight: 242.385
• Mol file: 27560-62-9.mol

Synonyms:bis(2-ethylphenyl) sulfide

Chemical Property of bis(2-ethylphenyl) sulfide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of bis(2-ethylphenyl) sulfide

There total 4 articles about bis(2-ethylphenyl) sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1-ethyl-2-iodobenzene (18282-40-1) + 2-ethylthiophenol (4500-58-7) → bis(2-ethylphenyl) sulfide (27560-62-9)

Guidance literature:

With copper(l) iodide; potassium carbonate; ethylene glycol; In tert-Amyl alcohol; at 120 ℃; for 16h;

DOI:10.1055/s-0029-1217986

Reference yield:

benzothiaferrole (12086-84-9) → bis(2-ethylphenyl) sulfide (27560-62-9) + ethylbenzene (100-41-4,27536-89-6) + 2-ethylthiophenol (4500-58-7) + 1,2-bis(2-ethylphenyl) disulfide (4500-66-7) + iron (7439-89-6)

Guidance literature:

With H₂; In hexane; react. of Fe-compound with H2 in hexane/anisol=125:1 in an autoclave cup (500 psig, 25°C), heating (175°C, 650 psig, 20 h); cooling and venting, filtn., GC-mass spectrometry for S-containing aromatics;

DOI:10.1021/om00095a024

Reference yield:

1-ethyl-2-iodobenzene (18282-40-1) → bis(2-ethylphenyl) sulfide (27560-62-9)

Guidance literature:

With carbon disulfide; copper(l) iodide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; at 110 ℃; for 18h; Inert atmosphere;

DOI:10.1002/anie.201801146

upstream raw materials:

benzothiaferrole

1-ethyl-2-iodobenzene

2-ethylthiophenol

Downstream raw materials:

C₁₆H₁₈O₂S