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High purity 7439-89-6 Iron powder
Cas No: 7439-89-6
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Iron CAS:7439-89-6 Safe delivery Free of customs clearance
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Iron HYDROGEN REDUCED IRON
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Iron
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7439-89-6 Usage

Health Hazard

Fire may produce irritating and/or toxic gases. Contact may cause burns to skin and eyes. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

Chemical properties

Gray metal; It should be dissolved in hydrochloric acid, sulfuric acid and dilute nitric acid.

Reactivity Profile

Iron is pyrophoric [Bretherick, 1979 p. 170-1]. A strong reducing agent and therefore incompatible with oxidizing agents. Burns in chlorine gas [Mellor 2, Supp. 1:380 1956]. Reacts with fluorine with incandescence [Mellor 13:314, 315, 1946-1947].

Toxicity

Iron Powder: GRAS (FDA, § 184.1375, 2000); Inhalation of dust can cause pneumoconiosis. Operation personnel should wear overall, wear dust masks and other labor insurance products. Production equipment should be closed, the workshop should be well-ventilated. Be sure to pay attention to dust protection.

History

Iron has been known to mankind from early civilization. In fact, a period of history, the “iron age,” is named for the widespread use of this metal. For almost a thousand years, it remained as the single most-used metal, and its use in mechanization made the industrial revolution possible.
Iron, after oxygen, silicon and aluminum, is the fourth most abundant element in the earth’s crust. It is the prime constituent of earth’s core along with nickel. Its abundance in the crust is 5.63%. Its concentration in the seawater is about 0.002mg/L. The principal ores of iron are hematite, Fe2O3; pyrite, Fe2S2; ilmenite, FeTiO3; magnetite, Fe3O4; siderite, Fe2CO3; and limonite [FeO(OH)]. It also is found in a number of minerals, such as corundum, as an impurity. It also is found in meteorites.
Iron occurs in every mammalian cell and is vital for life processes. It is bound to various proteins and found in blood and tissues. The iron-porphyrin or heme proteins include hemoglobin, myoglobin and various heme enzymes, such as cytochromes and peroxidases. Also, it occurs in non heme compounds, such as ferritin, siderophilin, and hemosiderin. Hemoglobin, found in the red blood cells, is responsible for transport of oxygen to the tissue cells and constitutes about two-thirds (mass) of all iron present in the human body. An adult human may contain about 4 to 6 grams of iron.

Content analysis

Accurately weigh approximately 200 mg of the sample and transfer it into a 300 ml Erlenmeyer flask, add 50 ml of a dilute sulfuric acid solution (TS-241). Use a plug containing a Bunsen valve (the production method is to insert a glass tube connected with a short segment of rubber tube to the plug. The side of the rubber tube has a long slit while the other side is inserted of a glass rod so that the gas can escape and the air can’t enter). The solution was heated on a steam bath to dissolve the iron. After cooling, dilute with 50 ml of freshly boiled and cooled water. Add 2 drops of the test solution (TS-162) to 0.1 mol/L
Apply cerium sulfate titration to until the red color becomes light blue color. Each ml of 0.1mol/L of high cerium sulfate are equivalent to 5.585 mg of iron (Fe).
The method is the same as that of "reduced iron (01219)”.

Fire Hazard

Flammable/combustible material. May be ignited by friction, heat, sparks or flames. Some may burn rapidly with flare burning effect. Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. Substance may be transported in a molten form at a temperature that may be above its flash point. May re-ignite after fire is extinguished.

General Description

A gray lustrous powder. Used in powder metallurgy and as a catalyst in chemical manufacture.

Uses

Alloyed with C, Mn, Cr, Ni, and other elements to form steels. Nutritional supplement in wheat flours, corn meal, grits and other cereal products. 55Fe and 59Fe used in tracer studies; the former in biological studies.

Production Methods

Most iron produced today is from its oxide minerals, hematite and magnetite. The process involves reducing mineral iron with carbon in a blast furIRON 411nace. There are several types of blast furnaces which vary in design and dimensions. The overall processes, however, are more or less the same. One such process is outlined below:
The mixture of ore, coke and limestone is fed into the blast furnace from the top. The materials are preheated to about 200°C in the top most zone. Hematite is partially reduced to magnetite and then to FeO by the ascending stream of carbon monoxide formed at the bottom and mid zones of the furnace resulting from high temperature oxidation of carbon. The ferrous oxide FeO formed at the top zone is reduced to metallic iron at about 700°C in the mid zone by carbon monoxide. A hot air blast at 900°C passes through the entire furnace for a very short time (usually for a few seconds). This prevents any gassolid reaction product from reaching equilibrium. In the temperature zone 700 to 1,200°C ferrous oxide is completely reduced to iron metal by carbon monoxide. Also, more CO is formed by oxidation of carbon by carbon dioxide. Further down the furnace at higher temperatures, around 1,500°C, iron melts, dripping down into the bottom. Also, in this temperature zone acidic silica particles react with basic calcium oxide produced from the decomposition of limestone, producing calcium silicate. The molten waste calcium silicate also drips down into the bottom. In the hottest zone of the blast furnace, between 1,500 to 2,000°C, some carbon dissolves into the molten iron. Also at these temperatures any remaining silicates and phosphates are reduced to silicon and phosphorus, and dissolve into the molten iron. Additionally, other tract metals such as manganese dissolve into the molten iron. The impure iron melt containing about 3 to 4% carbon is called “pig iron”. At the bottom, the molten waste slag floats over the impure pig iron melt that is heavier than the slag melt and immiscible with it. Pig iron is separated from the slag and purified for making different types of steel. Chemical reactions and processes occurring in various temperature zones of blast furnace are summarized below:  production method   Pig iron produced in the blast furnace is purified and converted to steel in a separate furnace, known as a basic-oxygen furnace. Jets of pure oxygen gas at high pressure are blown over and through the pig iron melt. Metal impurities are converted into oxides. Part of the dissolved carbon in the impure iron melt is converted into carbon dioxide gas. Formation of SiO2, CO2, and other metal oxides are exothermic reactions that raise the temperature to sustain the melt. A lime flux (CaO) also is added into the melt, which converts silica into calcium silicate, CaSiO3, and phosphorus into calcium phosphate, Ca3(PO4)2, forming a molten slag immiscible with molten steel. The lighter molten slag is decanted from the heavier molten steel.  

Air & Water Reactions

Highly flammable. May react with water to give off hydrogen, a flammable gas. The heat from this reaction may ignite the hydrogen.

Purification Methods

Clean it in conc HCl, rinse in de-ionised water, then reagent grade acetone and dry it under vacuum.

Mining

China pyrrhotite-type sulfur pyrite mine has less of mining hills resources. Take the MinXi mine in the DaTian City, Fujian Province and Zhangjiagou mine in Dandong City, Liaoning Province as the representatives; both of them are underground mining mines. The former applies the Housing pile mining method while the later one uses the section mining method. The pit mining process is the same as the method of "phosphate rock." Beneficiation methods include flotation process and flotation-magnetic combined process.

Uses

Industrial uses of iron as carbon steels are numerous and surpass any 410 IRONother alloys. Carbon steels are alloys of iron containing carbon in varying proportions, usually up to 1.7% carbon. Other metals also are incorporated into carbon steels to produce low-alloy steels. Such metals are usually nickel and chromium and are classified as stainless steel, tool steels, and heat-resistant steels. Non-steel iron alloys such as cast iron, wrought iron, nickel iron and silicon iron also have many important applications. Another important application of iron is as an industrial catalyst. It is used in catalyst compositions in the Haber process for synthesis of ammonia, and in Fischer-Tropsch process for producing synthetic gasoline.The followings are some examples of common applications:
  • pharmaceuticals, pesticides, powder metallurgy and so on;
  • as a hot hydrogen generator, gel propellant, combustion activator, catalyst, water cleaning adsorbent, sintered active agent, etc;used for powder metallurgy products, all kinds of mechanical parts and components products, cemented carbide products, etc;
  • as a reducing agent as well as being used for iron salt manufacturing and electronics industry;
  • as nutritional supplements (iron fortifier),for casting,or as reducing agent;
  • in the electronics industry, powder metallurgy.
InChI:InChI=1/Fe

7439-89-6 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Aldrich (266256)  Iron  wire, diam. 1.0 mm, ≥99.99% trace metals basis 7439-89-6 266256-15.5G 9,927.45CNY Detail
Aldrich (266256)  Iron  wire, diam. 1.0 mm, ≥99.99% trace metals basis 7439-89-6 266256-3.1G 2,990.52CNY Detail
Aldrich (266213)  Iron  rod, diam. 6.3 mm, 99.98% trace metals basis 7439-89-6 266213-150G 7,201.35CNY Detail
Aldrich (266213)  Iron  rod, diam. 6.3 mm, 99.98% trace metals basis 7439-89-6 266213-30G 2,122.38CNY Detail
Aldrich (413054)  Iron  granular, 10-40 mesh, >99.99% trace metals basis 7439-89-6 413054-25G 2,845.44CNY Detail
Aldrich (413054)  Iron  granular, 10-40 mesh, >99.99% trace metals basis 7439-89-6 413054-5G 810.81CNY Detail
Aldrich (338141)  Iron  foil, thickness 0.25 mm, ≥99.99% trace metals basis 7439-89-6 338141-6.25CM2 1,113.84CNY Detail
Aldrich (338141)  Iron  foil, thickness 0.25 mm, ≥99.99% trace metals basis 7439-89-6 338141-5G 3,099.33CNY Detail
Aldrich (338141)  Iron  foil, thickness 0.25 mm, ≥99.99% trace metals basis 7439-89-6 338141-25CM2 3,424.59CNY Detail
Aldrich (338141)  Iron  foil, thickness 0.25 mm, ≥99.99% trace metals basis 7439-89-6 338141-1.2G 1,009.71CNY Detail
Aldrich (267945)  Iron  chips, 99.98% trace metals basis 7439-89-6 267945-1KG 1,310.40CNY Detail
Aldrich (267945)  Iron  chips, 99.98% trace metals basis 7439-89-6 267945-250G 464.49CNY Detail

7439-89-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name Iron

1.2 Other means of identification

Product number -
Other names iron powder

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food Contaminant: METALS
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7439-89-6 SDS

7439-89-6Synthetic route

iron(III) oxide

iron(III) oxide

Conditions
ConditionsYield
With hydrogen In neat (no solvent) passing H2 over Fe2O3 at 350°C over period of 36 h, at 440°C 12 h or at 500°C in fast reaction;;100%
With H2 In neat (no solvent) passing H2 over Fe2O3 at 350°C over period of 36 h, at 440°C 12 h or at 500°C in fast reaction;;100%
With hydrogen In neat (no solvent) reduction of Fe2O3 at 600°C leads to formation of powdered Fe, at 1000°C formed Fe hardly fragile;;
goethite

goethite

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In neat (no solvent) Isothermal heat treatment for 2 h at 400°C.;100%
iron(II) chloride

iron(II) chloride

Conditions
ConditionsYield
With 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclo-hexadiene In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;100%
With hydrogen In neat (no solvent) heated with H2 at approx. 350 °C; formation of pyrophoric Fe;;
With aluminium trichloride; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In melt Electrochem. Process; (He or Ar); dissoln. of FeCl2 in AlCl3/1-ethyl-3-methyimidazoline chloride ionic liquid (room temp.), chronoamperometric electrodeposition (tungsten electrode substrate, -0.35 V vs. Fe/Fe(II), 120 s, room temp.);
LaFe(1+)
111496-23-2

LaFe(1+)

A

La(1+)

La(1+)

B

iron
7439-89-6

iron

Conditions
ConditionsYield
In gas collision induced dissocn. reaction (argon) in a mass spectrometer; energy range 17-78 eV; total pressure: 4E-6 Torr; not isolated;A 100%
B 100%
iron(III) oxide

iron(III) oxide

Conditions
ConditionsYield
With water; lithium chloride In melt at 660℃; for 5h; Inert atmosphere; Electrolysis;98.4%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

Cyclohepta-1,3-diene
876938-53-3

Cyclohepta-1,3-diene

A

tricarbonyl(η-3-cyclohepta-1,3-diene)iron
40674-86-0

tricarbonyl(η-3-cyclohepta-1,3-diene)iron

B

iron
7439-89-6

iron

Conditions
ConditionsYield
In dibutyl ether cycloheptadiene stirred in n-Bu2O while N2 bubbled through mixt. for 15h, Fe(CO)5 added, heated with stirring at 150°C for 44 h, cooled; filtered through Celite, evapd. in vac.;A 93%
B n/a
iron(III) chloride
7705-08-0

iron(III) chloride

lithium triethylborohydride
22560-16-3

lithium triethylborohydride

Conditions
ConditionsYield
In tetrahydrofuran FeCl3 in THF was added dropwise to stirring soln. of 12 ml LiBEt3H in THF (1.0 M), held at const. temp. under N2 atm.; forms of particles dependon dropping rate (1 drop/10s, 1/s, 2/s), stirring rate (200, 400, 1600 rpm) and temp.(0 - 60°C); vac. filtration, washed THF/EtOH (1:1), dried in vac.;90%
1-trimethylsilyl-μ3-S,S'-ethylenedithiolatohexacarbonyldiiron

1-trimethylsilyl-μ3-S,S'-ethylenedithiolatohexacarbonyldiiron

A

iron sulfide

iron sulfide

B

(CH3)3SiC2H3S8Fe7

(CH3)3SiC2H3S8Fe7

C

iron
7439-89-6

iron

D

4-Trimethylsilanyl-[1,3]dithiolan-2-one

4-Trimethylsilanyl-[1,3]dithiolan-2-one

E

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

Conditions
ConditionsYield
In decane byproducts: CH2CH2, CH3CHCH2, CO; Ar atmosphere; decompn. (165°C, 13 h); further products; GLC, chromato-mass spectroscopy;A n/a
B n/a
C n/a
D 5%
E 75%
(μ-dithio)bis(tricarbonyliron)
14243-23-3

(μ-dithio)bis(tricarbonyliron)

Fe3-μ-(o-C6H4CH2NPh)(CO)8

Fe3-μ-(o-C6H4CH2NPh)(CO)8

A

iron sulfide

iron sulfide

B

Fe2-μ-(o-C6H4CH2NPh)(CO)6

Fe2-μ-(o-C6H4CH2NPh)(CO)6

C

Fe3(CO)9S2

Fe3(CO)9S2

D

iron
7439-89-6

iron

Conditions
ConditionsYield
In n-heptane N2 atmosphere; stirring (70°C, 40 min); filtn., evapn., chromy. (silica gel);A n/a
B 66%
C 25%
D n/a
benzothiaferrole
12086-84-9

benzothiaferrole

A

2-thiocoumarin
3986-98-9

2-thiocoumarin

B

iron
7439-89-6

iron

C

Benzo[b]thiophene
95-15-8

Benzo[b]thiophene

Conditions
ConditionsYield
flash vac. pyrolysis in a Pyrex tube connected with a cold trap (E-5 Torr, 285-315°C); coating of the hot zone by Fe, rinsing of trap with acetone, GC;A <1
B n/a
C 63%
With ceric ammonium nitrate In acetone addn. of (NH4)2Ce(NO3)6 to a stirred soln. of Fe-compound in acetone (5 min, air), stirring for 2 h; monitored by TLC (hexane), filtn. (Celite), dilution of filtrate with ether, filtn. and evapn. to dryness, GLC of white crystals in acetone, TLC (CH2Cl2/hexane=1:1), (1)H NMR, IR, elem. anal.;A 35.5%
B 36%
C 4.4%
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

Conditions
ConditionsYield
In not given byproducts: CO; Sonication; soln. of Fe(CO)5 in diphenylmethane sonicated for 3 h under Ar at 30 °C to give iron nanoparticles; removed by centrifugation, washed with pentane, dried under vac., detd. by Moessbauer spectroscopy, XRD;53%
In further solvent(s) under Ar; thermolysis of Fe(CO)5 using heterogeneous nucleation technique (Proc. Phys. Soc. A 1949, 62, 562); diluted 2 times with octyl ether; Fe(CO)5 added (100°C); heated (260°C); cooled; EtOH (3:1 volume ratio to octyl ether); collected with magnet;40%
With cis-Octadecenoic acid In further solvent(s) under Ar; thermolysis of Fe(CO)5 using heterogeneous nucleation technique (Proc. Phys. Soc. A 1949, 62, 562); oleic acid:oleylamine 1:1 molar ratio; diluted 2 times with octyl ether; Fe(CO)5 added (100°C); heated (260°C); cooled; EtOH (3:1 volume ratio to octyl ether); collected with magnet;40%
lithiumpentamethylcyclopentadiene

lithiumpentamethylcyclopentadiene

ethanethiol
75-08-1

ethanethiol

iron(II) chloride

iron(II) chloride

A

bis(pentamethylcyclopentadienyl)iron(II)
12126-50-0

bis(pentamethylcyclopentadienyl)iron(II)

B

[(η5-pentamethylcyclopentadienyl)Fe(II)(μ2-SEt)3Fe(III)(η5-pentamethylcyclopentadienyl)]

[(η5-pentamethylcyclopentadienyl)Fe(II)(μ2-SEt)3Fe(III)(η5-pentamethylcyclopentadienyl)]

C

iron
7439-89-6

iron

Conditions
ConditionsYield
With n-BuLi In tetrahydrofuran; hexane under Ar; FeCl2 added at 0°C to stirred suspn. of (C5Me5)Li in THF; stirred (1 h); cooled to -78°C; suspn. prepared from n-BuLi inn-hexane and HSEt at 0°C added; 1 h at -78°C; warmed to r oom temp. with stirring overnight; evapd. to dryness; purified by column chromy. (neutral alumina, n-hexane); insol. solid washed with H2O (Fe); elem. anal.;A 9%
B 49%
C 15%
(η4-1,3-butadiene)tris(triethylphosphine)iron(0)
107339-80-0

(η4-1,3-butadiene)tris(triethylphosphine)iron(0)

A

bis(η4-1,3-butadiene)(triethylphosphino)iron(II)
103835-78-5

bis(η4-1,3-butadiene)(triethylphosphino)iron(II)

B

iron
7439-89-6

iron

Conditions
ConditionsYield
In tetrahydrofuran under Ar at 5°C;A 40%
B 40%
iron(II) bromide dimethoxyethane adduct
99611-53-7

iron(II) bromide dimethoxyethane adduct

potassium dimethylnopadienide
1421320-35-5

potassium dimethylnopadienide

A

[Fe(η5-dimethylnopadienyl)2]

[Fe(η5-dimethylnopadienyl)2]

B

iron
7439-89-6

iron

Conditions
ConditionsYield
In tetrahydrofuran; toluene at 20℃; for 4h; Inert atmosphere;A 28%
B n/a
Fe(CO)4(COCH2CH2O)

Fe(CO)4(COCH2CH2O)

A

1,3-DIOXOLANE
646-06-0

1,3-DIOXOLANE

B

iron
7439-89-6

iron

Conditions
ConditionsYield
With H2 In decalin High Pressure; 71.5 atm H2 at room temp., heated to 200°C and stirred for 24 h; pressure realesed, detn. by GC and GC-MS;A 27%
B n/a
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

A

triiron dodecarbonyl
17685-52-8

triiron dodecarbonyl

B

iron
7439-89-6

iron

Conditions
ConditionsYield
In n-heptane; decalin Sonication; 0°C (Ar); products identified IR, UV, mass spect., chromy.;A 9.8%
B n/a
In octane Sonication; 0°C (Ar); products identified IR, UV, mass spect., chromy.;A 6.9%
B n/a
In decalin Sonication; 0°C (Ar); 0.1 M Fe(CO)5; products identified IR, UV, mass spect., chromy.;A 4.7%
B n/a
iron pentacarbonyl
13463-40-6

iron pentacarbonyl

hydrogen
1333-74-0

hydrogen

A

iron(II,III) oxide

iron(II,III) oxide

B

iron(II) oxide
1345-25-1

iron(II) oxide

C

iron(III) oxide

iron(III) oxide

D

cementite

cementite

E

iron
7439-89-6

iron

Conditions
ConditionsYield
In neat (no solvent, gas phase) mixt. of vapor of Fe(CO)5 and H2 decomposed by plasma-chemical decomposition on Al2O3; monitored by XRD;A n/a
B n/a
C n/a
D 1%
E n/a
ferric nitrate
7782-61-8

ferric nitrate

Conditions
ConditionsYield
Stage #1: ferric nitrate at 450℃; for 8h;
Stage #2: With hydrogen at 500℃; for 16h;
In neat (no solvent) 15 min at 900°C under atomic hydrogen atmosphere;
With hydrogen In methanol Fe/MCM-41 prepd. by impregnation of MCM-41 with methanolic soln. of Fe(NO3)3 with stirring for 24 h under N2; catalyst filtered, washed with methanol, dried at 373 K and calcined at 773 K; catalyst reduced in H2 above 773 K;
C26H28Br2N4O4

C26H28Br2N4O4

Conditions
ConditionsYield
In tetrahydrofuran; methanol for 1h; Heating / reflux;
ammonium tris(bi(tetrazolato)amine)ferrate(III)

ammonium tris(bi(tetrazolato)amine)ferrate(III)

Conditions
ConditionsYield
Heating / reflux;
potassium carbonate
584-08-7

potassium carbonate

potassium ferrocyanide

potassium ferrocyanide

A

potassium cyanate
590-28-3

potassium cyanate

B

potassium cyanide

potassium cyanide

C

iron
7439-89-6

iron

Conditions
ConditionsYield
In melt at red heat; pression of KCN from iron sponge out;
In melt byproducts: N2; at red heat; extraction of KCN with H2O;
In melt at red heat; pression of KCN from iron sponge out;
ferrous(II) sulfate heptahydrate

ferrous(II) sulfate heptahydrate

ammonium chloride

ammonium chloride

Conditions
ConditionsYield
In water Electrolysis; electrolysis of aq. soln. of FeSO4*7H2O and NH3 leads to precipitation of light grey iron on cathode;;
zinc ferrite

zinc ferrite

A

iron
7439-89-6

iron

B

zinc
7440-66-6

zinc

Conditions
ConditionsYield
With H2 In neat (no solvent) sample heating in TG apparatus in 25% H2/He (50 ml/min) at 5 K/min up to800°C; TG;
iron(III) oxide

iron(III) oxide

Conditions
ConditionsYield
With hydrogen In neat (no solvent) Kinetics; byproducts: H2O; 300°C, carrier gas N2 or Ar + CH4 or CH4 + Ar + CO or air;
With hydrogen In gaseous matrix Kinetics; byproducts: H2O; sample redn. by 10% H2/Ar at 15 K/min up to 1000 K;
With hydrogen; gold In gaseous matrix Kinetics; byproducts: H2O; Au/Fe2O3 mixt. heating at 15 K/min in 10% H2/Ar (24 ml/min) up to 1260 K;
With hydrogen In gaseous matrix Kinetics; byproducts: H2O; sample heating at 15 K/min in 10% H2/Ar (24 ml/min) up to 1260 K;
iron oxide

iron oxide

Conditions
ConditionsYield
In sodium hydroxide aq. NaOH; Electrolysis; in 50 wt % NaOH/water electrolyte at 110°C using Pt cylinder counter electrode and steel/adsorbed hematite as cathode; at -1.2 V vs. Hg/HgO;
With hydrogen hematite redn. at 500°C under hydrogen;
iron oxide

iron oxide

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
In neat (no solvent) Kinetics; reduced at 252.5-383°C under conditions without an external diffusion effect; TEM;
iron(II) metasilicate

iron(II) metasilicate

Conditions
ConditionsYield
In solid Electrolysis; electrolyzing molten FeSiO3 with addn. of either CaO or MgO leads to pptn. of Fe on cathode;;
In neat (no solvent) no redn. of feO to Fe in a stream of H at 850°C;;0%
In neat (no solvent) no redn. of feO to Fe in a stream of H at 850°C;;0%
sodium iron(III) pyrophosphate

sodium iron(III) pyrophosphate

Conditions
ConditionsYield
In not given Electrolysis; electrolyzing soln. of NaFeP2O7 with bath potential 4 V;; contains Fe2O3 and pyrophosphorous acid;;
iron(II) chloride tetrahydrate

iron(II) chloride tetrahydrate

Conditions
ConditionsYield
In water Electrolysis; electrolyzing soln. FeCl2*4H2O and NaCl (addn. of little HCl to clear soln.) at 50 to 70°C with current efficiency of 95 %;;
With ammonia In ethanol n-type Si(100) substrate coated with drop of soln. FeCl2*4H2O; dried; loaded on quartz boat into quartz tube reactor; heated under Ar; treated by NH3 with flow rate of 20 sccm for 1-10 min;
With sodium hydroxide In further solvent(s) heating FeCl2*4H2O and NaOH in propylene glycol; X-ray diffraction;
4,4-dimethyl-3-(2-nitrobenzyl)-2-oxazolidinone
907994-35-8

4,4-dimethyl-3-(2-nitrobenzyl)-2-oxazolidinone

4,4-dimethyl-3-(2-aminobenzyl)-2-oxazolidinone
907993-76-4

4,4-dimethyl-3-(2-aminobenzyl)-2-oxazolidinone

Conditions
ConditionsYield
With ammonium chloride In ethanol; water100%
5-methyl-3-(2-nitrobenzyl)-2-oxazolidinethione
907994-36-9

5-methyl-3-(2-nitrobenzyl)-2-oxazolidinethione

5-methyl-3-(2-aminobenzyl)-2-oxazolidinethione
907993-79-7

5-methyl-3-(2-aminobenzyl)-2-oxazolidinethione

Conditions
ConditionsYield
With ammonium chloride In ethanol; water100%
5-ethyl-3-(2-nitrobenzyl)-2-oxazolidinone
907994-37-0

5-ethyl-3-(2-nitrobenzyl)-2-oxazolidinone

5-ethyl-3-(2-aminobenzyl)-2-oxazolidinone
907993-80-0

5-ethyl-3-(2-aminobenzyl)-2-oxazolidinone

Conditions
ConditionsYield
With ammonium chloride In ethanol; water100%
5,5-dimethyl-3-(2-nitrobenzyl)thiazolidine-2-one
907994-43-8

5,5-dimethyl-3-(2-nitrobenzyl)thiazolidine-2-one

3-(2-aminobenzyl)-5,5-dimethylthiazolidine-2-one
907994-20-1

3-(2-aminobenzyl)-5,5-dimethylthiazolidine-2-one

Conditions
ConditionsYield
With ammonium chloride In ethanol; water100%
3-hexyl-6-methyl-6-(3-nitrophenyl)-3-azabicyclo[3.1.0]hexan-2-one
280759-64-0

3-hexyl-6-methyl-6-(3-nitrophenyl)-3-azabicyclo[3.1.0]hexan-2-one

6-(3-Aminophenyl)-3-hexyl-6-methyl-3-azabicyclo[3.1.0]hexan-2-one

6-(3-Aminophenyl)-3-hexyl-6-methyl-3-azabicyclo[3.1.0]hexan-2-one

Conditions
ConditionsYield
With calcium chloride In ethanol; water100%
3-hexyl-6-isopropyl-6-(3-nitrophenyl)-3-azabicyclo[3.1.0]hexane

3-hexyl-6-isopropyl-6-(3-nitrophenyl)-3-azabicyclo[3.1.0]hexane

3-(3-hexyl-6-isopropyl-3-azabicyclo[3.1.0]hex-6-yl)aniline

3-(3-hexyl-6-isopropyl-3-azabicyclo[3.1.0]hex-6-yl)aniline

Conditions
ConditionsYield
With calcium chloride In ethanol; dichloromethane; water100%
3-hexyl-6-(3-nitrophenyl)-6-propyl-3-azabicyclo[3.1.0]hexane

3-hexyl-6-(3-nitrophenyl)-6-propyl-3-azabicyclo[3.1.0]hexane

3-(3-hexyl-6-propyl-3-azabicyclo[3.1.0]hex-6-yl)aniline

3-(3-hexyl-6-propyl-3-azabicyclo[3.1.0]hex-6-yl)aniline

Conditions
ConditionsYield
With calcium chloride In ethanol; dichloromethane; water100%
3-Hexyl-6-(3-nitrophenyl)-6-(2,2,2-trifluoroethyl)-3-azabicyclo[3.1.0]hexane-2,4-dione

3-Hexyl-6-(3-nitrophenyl)-6-(2,2,2-trifluoroethyl)-3-azabicyclo[3.1.0]hexane-2,4-dione

3-Hexyl-6-(3-aminophenyl)-6-(2,2,2-trifluoroethyl)-3-azabicyclo[3.1.0]hexane-2,4-dione

3-Hexyl-6-(3-aminophenyl)-6-(2,2,2-trifluoroethyl)-3-azabicyclo[3.1.0]hexane-2,4-dione

Conditions
ConditionsYield
With calcium chloride In ethanol; dichloromethane; water100%
hydrogenchloride
7647-01-0

hydrogenchloride

water
7732-18-5

water

iron(II) chloride tetrahydrate

iron(II) chloride tetrahydrate

Conditions
ConditionsYield
In water soln. of Fe in concd. HCl was refluxed; ppt. filtered off, washed with Et2O, dried in vac.;100%
In hydrogenchloride evapn. a soln. of iron filings in dild. aq. HCl over iron filings until the hot soln. starts foaming; crystn. on cooling;; filtn.; crystn.; drying in a stream of dry air at 30-40°C;;
In hydrogenchloride evapn. a soln. of iron filings in dild. aq. HCl over iron filings until the hot soln. starts foaming; crystn. on cooling;; filtn.; crystn.; drying in a stream of dry air at 30-40°C;;
In water slight excess of 0.1 M hydrochloric acid added to iron powder, heated to dissolution; evapd.;
In hydrogenchloride iron powder and aq. HCl;
formic acid
64-18-6

formic acid

water
7732-18-5

water

iron(II) formate dihydrate

iron(II) formate dihydrate

Conditions
ConditionsYield
at 250℃; for 16h; Inert atmosphere;100%
In not given HCOOH was neutralized with Fe at 70-80°C; filtered, concd., cooled to room temp., recrystd. from water, dried in air;
Inert atmosphere;
Inert atmosphere;
In neat (no solvent) at 80℃;
5,10,15,20-tetraphenyl-21H,23H-porphine
917-23-7

5,10,15,20-tetraphenyl-21H,23H-porphine

5,10,15,20-tetraphenyl porphyrin iron
16591-56-3

5,10,15,20-tetraphenyl porphyrin iron

Conditions
ConditionsYield
In toluene byproducts: H2; cocondensation of iron and toluene vapor at liq. nitrogen temp.; heating to -94.6°C; dropwise addn. of porphine soln. under nitrogen to the slurry (molar ratio Fe:porphine 4:1); gradually warming to 0°C, 1h; filtration; evapn. of filtrate;100%
With Ag(111) In neat (no solvent) deposition of porphyrin deriv. onto silver by evapn. at 638 K, removing excess of porphyrin at 550 K, deposition of stoich. amount of iron; Buchner F., Schwald V., Cmanici K., Steinrueck H.-P., Marbach H. ChemPhysChem 2007, 8, 241-243; XPS and UPS;
picrolonic acid
132-42-3

picrolonic acid

iron picrolonate*H2O

iron picrolonate*H2O

Conditions
ConditionsYield
With HClO4 In water iron fillings dissolve in dilute HClO4, added aq. NaOH, resulting soln. added to aq. picrolonic acid at room temp.; ppt. filtered, washed with water, ethanol, ether, dried in vac. till constant weight, elem. anal.;100%
lithium nitride

lithium nitride

nitrogen
7727-37-9

nitrogen

Li2.7Fe0.3N

Li2.7Fe0.3N

Conditions
ConditionsYield
In neat (no solvent) Li3N fused in pure iron vessel; sealed under 300 kPa of N2; heated at 850-1050°C for 12 h; thermally quenched; detd. by X-ray powder diffraction;100%
uranium

uranium

selenium
7782-49-2

selenium

UFeSe3

UFeSe3

Conditions
ConditionsYield
In melt (Ar glovebox) U, Fe and Se were placed in fused-silica ampoule, evacuated to about 1E-4 Torr, sealed, heated to 1173 K in 30 h, maintained at 1173 K for 2 days, cooled to 773 K in 6 days, maintained at 773 K for 2 days, cooled to 298 K over 6 h; washed with water and dried with acetone, XRD;100%
1-(4-(7-(2-fluoro-4-nitrophenoxy)thieno[3,2-b]pyridin-2-yl)benzyl)pyrrolidin-2-one
1342835-29-3

1-(4-(7-(2-fluoro-4-nitrophenoxy)thieno[3,2-b]pyridin-2-yl)benzyl)pyrrolidin-2-one

1-(4-(7-(4-amino-2-fluorophenoxy)thieno[3,2-b]pyridin-2-yl)benzyl)pyrrolidin-2-one
1342835-31-7

1-(4-(7-(4-amino-2-fluorophenoxy)thieno[3,2-b]pyridin-2-yl)benzyl)pyrrolidin-2-one

Conditions
ConditionsYield
With ammonium chloride In water100%
hydrogenchloride
7647-01-0

hydrogenchloride

Fe(57)Cl2

Fe(57)Cl2

Conditions
ConditionsYield
In water at 60℃; for 47h;100%
zinc diacetate
557-34-6

zinc diacetate

oxalic acid
144-62-7

oxalic acid

(x)Ni(2+)*(1-x)Zn(2+)*2Fe(2+)*3C2O4(2-)*99H2O

(x)Ni(2+)*(1-x)Zn(2+)*2Fe(2+)*3C2O4(2-)*99H2O

Conditions
ConditionsYield
In acetic acid heating of iron powder in a twofold excess of 1.5-2.0 M acetic acid under a N2 atmosphere; stirring; addn. of a soln. of Zn(2+) and Ni(2+) acetate; boilig; addn. of 3-5% excess 1 M oxalic acid; boiling for 1 h; filtration;; washing and drying at 100°C;;99.8%
In acetic acid heating of iron powder in a twofold excess of 1.5-2.0 M acetic acid under a N2 atmosphere; stirring; addn. of a soln. of Zn(2+) and Ni(2+) acetate; boilig; addn. of 3-5% excess 1 M oxalic acid; boiling for 1 h;; frozen ppt. with liquid N2 (with total mother soln.) and then freeze dried;;
2,6-dichlorotoluene
118-69-4

2,6-dichlorotoluene

2,4-dichloro-3-methylbromobenzene
127049-87-0

2,4-dichloro-3-methylbromobenzene

Conditions
ConditionsYield
With bromine; iodine In tetrachloromethane; (2S)-N-methyl-1-phenylpropan-2-amine hydrate99.5%
3-allyl-6-methyl-6-(3-nitrophenyl)-3-azabicyclo[3.1.0]hexan-2-one

3-allyl-6-methyl-6-(3-nitrophenyl)-3-azabicyclo[3.1.0]hexan-2-one

3-allyl-6-(3-aminophenyl)-6-methyl-3-azabicyclo[3.1.0]hexan-2-one

3-allyl-6-(3-aminophenyl)-6-methyl-3-azabicyclo[3.1.0]hexan-2-one

Conditions
ConditionsYield
With calcium chloride In methanol; ethanol; dichloromethane; water99%
2,6-dibromo-4-nitro-pyridine 1-oxide
98027-81-7

2,6-dibromo-4-nitro-pyridine 1-oxide

4-amino-2,6-dibromopyridine
39771-34-1

4-amino-2,6-dibromopyridine

Conditions
ConditionsYield
With acetic acid99%
ferrous(II) sulfate heptahydrate

ferrous(II) sulfate heptahydrate

2,2,4-trimethyl-4-[5-nitro-3-(3-phenylprop-2-ynyloxy)phenyl]-1,3-dioxolane
131341-02-1

2,2,4-trimethyl-4-[5-nitro-3-(3-phenylprop-2-ynyloxy)phenyl]-1,3-dioxolane

4-[5-amino-3-(3-phenylprop-2-ynyloxy)phenyl]-2,2,4-trimethyl-1,3-dioxolane

4-[5-amino-3-(3-phenylprop-2-ynyloxy)phenyl]-2,2,4-trimethyl-1,3-dioxolane

Conditions
ConditionsYield
With hydrogenchloride; triethylamine In methanol; water99%
sodium bicarbonate water

sodium bicarbonate water

4-nitro-1-(4-trifluoromethoxyphenoxy)-2-trifluoromethylbenzene
875774-88-2

4-nitro-1-(4-trifluoromethoxyphenoxy)-2-trifluoromethylbenzene

4-(4-trifluoromethoxyphenoxy)-3-trifluoromethyl-aniline
875774-55-3

4-(4-trifluoromethoxyphenoxy)-3-trifluoromethyl-aniline

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water; ethyl acetate99%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

iron(III) triflate - dimethylsulfoxide (1/6.2)

iron(III) triflate - dimethylsulfoxide (1/6.2)

Conditions
ConditionsYield
With oxygen In dimethyl sulfoxide metal. Fe under O2 atm. treated with DMSO and triflic acid (3 equiv.) in3 portions, heated at 100°C for 24 h;99%
picoline
108-89-4

picoline

thiourea
17356-08-0

thiourea

[4-methylpyridinium]2[Fe(isothiocyanate)4(4-methylpyridine)2]*2(4-methylpyridine)

[4-methylpyridinium]2[Fe(isothiocyanate)4(4-methylpyridine)2]*2(4-methylpyridine)

Conditions
ConditionsYield
In further solvent(s) under Ar atm. using Schlenk techniques; metal powder, thiourea (excess),4-methylpyridine refluxed overnight; soln. refluxed for 4 ds; soln. coo led to room temp.; soln. layered (hexane); crystn.;99%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

iron(II) triflate

iron(II) triflate

Conditions
ConditionsYield
In water stoich., Fe powder dissolved in aq. soln. of CF3SO3H by heating; ppt. filtered, dried (air), elem. anal.;99%
In water metal compd. dissolved in aq. soln. of triflic acid; filtered, cocd., crystd., dried at 200°C for several h;
In water mixed, warmed in water;
6,6-Diphenylfulvene
2175-90-8

6,6-Diphenylfulvene

1,1'-bis(diphenylmethyl)ferrocene

1,1'-bis(diphenylmethyl)ferrocene

Conditions
ConditionsYield
In acetonitrile Electrolysis; iron anode, 0.1 M tetraethylammonium bromide base electrolyte, inert atmosphere, 40°C, current density 5 mA/cm*2; pptn. on water diln., collection (filtn.), dissoln. (acetone), repptn. on hexane addn., recrystn. (acetone);99%
In dimethyl sulfoxide Electrolysis; iron anode, sodium bromide base electrolyte, inert atmosphere, 40°C, current density 5 mA/cm*2; pptn. on water diln., collection (filtn.), dissoln. (acetone), repptn. on hexane addn., recrystn. (acetone);<80

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