NORBORNENYLETHYLTRICHLOROSILANE

Base Information

• Chemical Name: NORBORNENYLETHYLTRICHLOROSILANE
• CAS No.: 14319-64-3
• Molecular Formula: C9H13Cl3Si
• Molecular Weight: 227.593
• Hs Code.: 2931900090
• Mol file: 14319-64-3.mol

Synonyms:Silane,bicyclo[2.2.1]hept-5-en-2-yltrichloro- (9CI);Silane,trichloro-5-norbornen-2-yl- (6CI,7CI,8CI);5-(Trichlorosilyl)-2-norbornene;Trichloro(5-norbornen-2-yl)silane;

Chemical Property of NORBORNENYLETHYLTRICHLOROSILANE

Chemical Property:

• Vapor Pressure: 0.164mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.4988
• Boiling Point: 246.322 °C at 760 mmHg
• Flash Point: 115.657 °C
• PSA: 0.00000
• Density: 1.286 g/cm³
• LogP: 3.60790

Purity/Quality:

98%,99%, ^*data from raw suppliers

5-(BICYCLOHEPTENYL)TRICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of NORBORNENYLETHYLTRICHLOROSILANE

There total 7 articles about NORBORNENYLETHYLTRICHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

trichlorovinylsilane (75-94-5) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → (Bicyclo<2.2.1>hept-5-en-2-yl)trichlorsilan (14319-64-3)

Guidance literature:

DOI:10.1016/0022-328X(94)88024-7

Reference yield: 85.0%

trichlorovinylsilane (75-94-5) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → (Bicyclo<2.2.1>hept-5-en-2-yl)trichlorsilan (14319-64-3) + 2,2-dichlor-3-neopentyl-2-silanorborn-5-en (204379-82-8) + dicyclopentadienylvinylchlorsilan

Guidance literature:

With tert.-butyl lithium; In pentane; at -78 - 25 ℃;

DOI:10.1016/0022-328X(88)80318-8

Reference yield: 85.0%

trichlorovinylsilane (75-94-5) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → (Bicyclo<2.2.1>hept-5-en-2-yl)trichlorsilan (14319-64-3) + 2,2-dichlor-3-neopentyl-2-silanorborn-5-en (204379-82-8) + dicyclopentadienylvinylchlorsilan + 3-tert-Butyl-1,1-dichloro-2,4-di-cyclopenta-2,4-dienyl-[1,3]disiletane + 1,3-Di-tert-butyl-1-chloro-2,4-di-cyclopenta-2,4-dienyl-[1,3]disiletane + 1-tert-Butyl-1,3-dichloro-2,4-di-cyclopenta-2,4-dienyl-3-(2-methyl-propenyl)-[1,3]disiletane

Guidance literature:

In pentane; at -78 - 25 ℃; Product distribution; Mechanism; var. quant. t-BuLi; var. temp;;

DOI:10.1016/0022-328X(88)80318-8

upstream raw materials:

trichlorovinylsilane

cyclopenta-1,3-diene

bicyclo[2.2.1]hepta-2,5-diene

Downstream raw materials:

Bicyclo[2.2.1]hept-5-en-2-yl-dichloro-phenyl-silane

2-norbornyltrifluorosilane

2-norbornyltrichlorosilane

Refernces

• 1、 Auner. "-". . p. 275 - 296. Retrieved 2007/10/02.