Trichlorovinylsilane

Base Information

• Chemical Name: Trichlorovinylsilane
• CAS No.: 75-94-5
• Deprecated CAS: 127290-37-3
• Molecular Formula: C2H3Cl3Si
• Molecular Weight: 161.49
• Hs Code.: 29319090
• European Community (EC) Number: 200-917-8
• NSC Number: 93872
• UN Number: 1305
• UNII: Q423F9NPBA
• DSSTox Substance ID: DTXSID8026430
• Nikkaji Number: J5.505K
• Wikidata: Q27286971
• Mol file: 75-94-5.mol

Synonyms:trichlorovinylsilane

Chemical Property of Trichlorovinylsilane

Chemical Property:

• Appearance/Colour: colorless to pale yellow fuming liquid with a pungent odor
• Vapor Pressure: 60 mm Hg ( 23 °C)
• Melting Point: -95 °C
• Refractive Index: n20/D 1.436(lit.)
• Boiling Point: 91.5 °C at 760 mmHg
• Flash Point: 10.6 °C
• PSA: 0.00000
• Density: 1.276 g/cm³
• LogP: 2.36690
• Storage Temp.: 0-6°C
• Sensitive.: Moisture Sensitive
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 159.906960
• Heavy Atom Count: 6
• Complexity: 54.3
• Transport DOT Label: Flammable Liquid Corrosive

Purity/Quality:

99% ^*data from raw suppliers

Trichlorovinylsilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, C
• Hazard Codes: F,C
• Statements: 11-14-20/21/22-34-20-37-35
• Safety Statements: 16-26-36/37/39-45-8-30-29

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Toxic Gases & Vapors -> Chlorosilanes
• Canonical SMILES: C=C[Si](Cl)(Cl)Cl
• Uses: Intermediate for silicones, coupling agent in adhesives and bonds. A study reports the possible use of this silane for treating Pluronic F127, chitosan for better attachment and proliferation of endothelial cells on biomaterials. Trichlorovinylsilane may be used to prepare epoxy terminated carbosiloxane.

Technology Process of Trichlorovinylsilane

There total 34 articles about Trichlorovinylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

acetylene (74-86-2,25067-58-7) → trichlorovinylsilane (75-94-5)

Guidance literature:

With tris(triphenylphosphine)ruthenium(II) chloride; trichlorosilane; In xylene; at 80 ℃; for 3h;

DOI:10.1016/S0022-328X(00)93320-5

Reference yield: 88.0%

tetravinylsilane (1112-55-6) → dichlorodivinylsilane (1745-72-8) + trichlorovinylsilane (75-94-5) + chlorotrivinylsilane (1871-21-2)

Guidance literature:

With hydrogenchloride; iron(III) chloride; at 24 - 52 ℃; Product distribution; oth. catalysts;

Reference yield: 73.0%

chlorotrivinylsilane (1871-21-2) → (n-pr-2-Cl)SiCl3 (7787-89-5) + dichlorodivinylsilane (1745-72-8) + trichlorovinylsilane (75-94-5)

Guidance literature:

With hydrogenchloride; iron(III) chloride; at 24 - 52 ℃; Product distribution;

upstream raw materials:

ethyltrichlorosilane

chloroethylene

trichloro(2-chloroethyl)silane

acetylene

Downstream raw materials:

(vinyl)trimethoxylsilane

1,3-divinyl-1,1,3,3-tetramethoxydisiloxane

1,1,3,5,5-pentamethoxy-1,3,5-trivinyl-trisiloxane

Triethoxyvinylsilane

Refernces

• 1、 -. "PROCESS FOR PREPARATION OF ALKOXYSILANES". Page 8-9. . Retrieved 2008/06/13.
• 2、 Chernyshev,Komalenkova,Kapitova,Bykovchenko,Khromykh,Bochkarev. "Gas-Phase Reactions of Hexachlorodisilane with Vinyl Chloride and Allyl Chloride". . p. 1447 - 1450. Retrieved 2007/10/03.