4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

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Chemical Name:4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene
CAS No.:75233-55-5
Molecular Formula:C₁₅H₂₆O₅
Molecular Weight:286.368
Hs Code.:

Synonyms:4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

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Chemical Property of 4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

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Technology Process of 4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

There total 3 articles about 4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 75233-47-5
1-Oxo-3-(2,4,7-trioxaoct-1-yl)-8-methyl-2-oxaspiro<4.5>-deca-6,10-diene

: 75233-55-5
4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃; for 0.5h;
DOI:10.1021/jo01312a003

Reference yield:

: 20646-36-0
4-methylcyclohexa-2,5-diene-1-carboxylic acid

: 75233-55-5
4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

Guidance literature:: Multi-step reaction with 3 steps

1: boron trifluoride etherate / 24 h / Heating

2: 1) 2,2,6,6-tetramethylpiperidine, n-butyllithium / 1) THF, hexane, 0 deg C, 15 min; 2) THF, -78 deg C; room temp., 2 h

3: 74 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 °C

With 2,2,6,6-tetramethyl-piperidine; lithium aluminium tetrahydride; n-butyllithium; boron trifluoride diethyl etherate; In diethyl ether;
DOI:10.1021/jo01312a003

Reference yield:

: 75233-44-2
methyl 4-methylcyclohexa-2,5-diene-1-carboxylate

: 75233-55-5
4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 2,2,6,6-tetramethylpiperidine, n-butyllithium / 1) THF, hexane, 0 deg C, 15 min; 2) THF, -78 deg C; room temp., 2 h

2: 74 percent / LiAlH₄ / diethyl ether / 0.5 h / 0 °C

With 2,2,6,6-tetramethyl-piperidine; lithium aluminium tetrahydride; n-butyllithium; In diethyl ether;
DOI:10.1021/jo01312a003