20646-36-0Relevant articles and documents
Synthetic Studies toward Verrucarol. 1. Synthesis of the AB Ring System
Kraus, George A.,Frazier, Kevin
, p. 4820 - 4825 (1980)
A synthetic route to the AB ring system of verrucarol is described.After two routes employing intramolecular cyclization failed, the Diels-Alder reaction of methyl coumalate and isoprene afforded bicyclic lactone 13.Transformation of 13 into hydroxy lacto
A HYBRID BIRCH-CLAISEN METHODOLOGY FOR ARYLATION AT ALLYLIC TERMINI: SYNTHESIS OF (+/-)-HERBERTENE
Chandrasekaran, S.,Turner, John V.
, p. 3799 - 3802 (2007/10/02)
A hybrid Birch-Claisen methodology has been developed for the regio- and stereo-controlled arylation of allyl groups, and applied to a synthesis of (+/-)-herbertene.