20646-36-0

Upstream product

• 99-94-5 p-Toluic acid 
• 64-17-5 ethanol 
• 7664-41-7 ammonia 

Downstream Products

• 75233-44-2 methyl 4-methylcyclohexa-2,5-diene-1-carboxylate 
• 84379-68-0 4-Methyl-cyclohexa-2,5-dienecarboxylic acid 2,3-dimethyl-cyclopent-2-enyl ester 
• 31673-50-4 4-methyl-1,5-cyclohexadiene-1-carboxylic acid 
• 110452-35-2 2-methylbenzene-1,3,5-tricarboxaldehyde 
• 75233-55-5 4-methyl-1-(hydroxymethyl)-1-(2-hydroxy-4,6,9-trioxodec-1-yl)-2,5-cyclohexadiene 
• 75233-45-3 1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-3-hydroxy-prop-1-yl>-4-methyl-2,5-cyclohexadiene 
• 75233-56-6 1-<(Benzoyloxy)methyl>-1-<2-(benzoyloxy)-4,6,9-trioxodec-1-yl>-4-methyl-2,5-cyclohexadiene 
• 84379-67-9 4-Methyl-cyclohexa-2,5-dienecarboxylic acid (E)-but-2-enyl ester 

Relevant academic research and scientific papers

Synthetic Studies toward Verrucarol. 1. Synthesis of the AB Ring System

A synthetic route to the AB ring system of verrucarol is described.After two routes employing intramolecular cyclization failed, the Diels-Alder reaction of methyl coumalate and isoprene afforded bicyclic lactone 13.Transformation of 13 into hydroxy lacto

Synthesis Based on Cyclohexadienes. Part 8. Synthesis of 1-Methylbicyclooct-2-enecarboxylate Derivatives

The 1,4-dihydrotoluic acids, obtained by the Birch reduction of 2-methyl- and 3-methyl-benzoic acids are isomerised to 2-methylcyclohexa-1,5-diene-1-carboxylic acid 10 and 5-methylcyclohexa-1,5-diene-1-carboxylic acid 15, respectively.These cojugated dien

A HYBRID BIRCH-CLAISEN METHODOLOGY FOR ARYLATION AT ALLYLIC TERMINI: SYNTHESIS OF (+/-)-HERBERTENE

A hybrid Birch-Claisen methodology has been developed for the regio- and stereo-controlled arylation of allyl groups, and applied to a synthesis of (+/-)-herbertene.