Technology Process of C31H39N2O2Si(1+)*Cl(1-)
There total 5 articles about C31H39N2O2Si(1+)*Cl(1-) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
3-bromo-4-methylbenzoic acid tert-butyl ester;
With
tert.-butyl lithium;
In
tetrahydrofuran;
at -78 ℃;
for 1h;
Inert atmosphere;
3,7-bis(N,N-dimethylamino)-5,5-dimethyldibenzo[b,e]silin-10(5H)-one;
In
tetrahydrofuran;
at -78 - 20 ℃;
for 2h;
Inert atmosphere;
With
hydrogenchloride;
In
water;
Inert atmosphere;
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: dmap / tetrahydrofuran / Reflux
2.1: tert.-butyl lithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 - 20 °C / Inert atmosphere
2.3: Inert atmosphere
With
dmap; tert.-butyl lithium;
In
tetrahydrofuran;
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: acetic acid / 0.5 h / 60 °C
2.1: sec.-butyllithium / tetrahydrofuran; hexane / 2.5 h / -78 °C
2.2: 2 h / 20 °C
3.1: potassium permanganate / acetone / 2.5 h / -15 °C
4.1: tert.-butyl lithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere
4.2: 2 h / -78 - 20 °C / Inert atmosphere
4.3: Inert atmosphere
With
potassium permanganate; tert.-butyl lithium; sec.-butyllithium; acetic acid;
In
tetrahydrofuran; hexane; acetone;