2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

Base Information

Chemical Name:2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone
CAS No.:244633-57-6
Molecular Formula:C₁₃H₁₉ClO₄
Molecular Weight:274.744
Hs Code.:

Synonyms:2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

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Chemical Property of 2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

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Technology Process of 2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

There total 1 articles about 2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 244633-54-3
6,7-O-cyclohexylidene-3,5-dideoxy-D-xylo-heptono-1,4-lactone

: 244633-57-6
2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

: 6,7-O-cyclohexylidene-3,5-dideoxy-2-O-(p-toluenesulfonyl)-D-xylo-heptono-1,4-lactone

Guidance literature:: With pyridine; at 0 - 20 ℃;
DOI:10.1021/jo990445+

Reference yield:

: 244633-57-6
2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

: 1723-00-8,83680-83-5
(R)-(+)-pipecolic acid

Guidance literature:: Multi-step reaction with 6 steps

1: 89 percent / sodium azide / dimethylformamide / 24 h / 20 °C

2: 85 percent / hydrogen / Pd/charcoal / ethyl acetate / 1 h / Heating

3: 0.70 g / NaHCO₃ / ethyl acetate; H₂O / 3 h

4: 94 percent / HCl / methanol; H₂O / Heating

5: sodium periodate / methanol / 3 h

6: 12 mg / hydrogen; glacial acetic acid / Pd-C / ethanol

With hydrogenchloride; sodium periodate; sodium azide; hydrogen; sodium hydrogencarbonate; acetic acid; palladium on activated charcoal; In methanol; ethanol; water; ethyl acetate; N,N-dimethyl-formamide; 1: Substitution / 2: Hydrogenation / 3: Acylation / 4: Hydrolysis / 5: Oxidation / 6: Hydrogenolysis;
DOI:10.1021/jo990445+

Reference yield:

: 244633-57-6
2-chloro-6,7-O-cyclohexylidene-2,3,5-trideoxy-D-lyxo-heptono-1,4-lactone

: 244633-64-5
5-(N-benzyloxycarbonyl)amino-2,4,5-trideoxy-L-threo-hexurono-6,3-lactone

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / sodium azide / dimethylformamide / 24 h / 20 °C

2: 85 percent / hydrogen / Pd/charcoal / ethyl acetate / 1 h / Heating

3: 0.70 g / NaHCO₃ / ethyl acetate; H₂O / 3 h

4: 94 percent / HCl / methanol; H₂O / Heating

5: sodium periodate / methanol / 3 h

With hydrogenchloride; sodium periodate; sodium azide; hydrogen; sodium hydrogencarbonate; palladium on activated charcoal; In methanol; water; ethyl acetate; N,N-dimethyl-formamide; 1: Substitution / 2: Hydrogenation / 3: Acylation / 4: Hydrolysis / 5: Oxidation;
DOI:10.1021/jo990445+