1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

Base Information

Chemical Name:1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole
CAS No.:1394958-96-3
Molecular Formula:C₇₄H₈₀N₂O₄Si₂
Molecular Weight:1117.63
Hs Code.:

1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

Synonyms:1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

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Chemical Property of 1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

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Technology Process of 1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

There total 6 articles about 1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1394958-95-2
{6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane

: 174621-52-4
N-(4-bromophenyl)-1H-indole

: 1394958-96-3
1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

Guidance literature:: N-(4-bromophenyl)-1H-indole; With n-butyllithium; In tetrahydrofuran; at -78 - -10 ℃; for 1h; Inert atmosphere;

{6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane; In tetrahydrofuran; at -10 ℃; for 3h; Inert atmosphere;
DOI:10.1039/c2cc34176j

Reference yield: 85.0%

: 1394958-95-2
{6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane

: 1528767-87-4
C₁₄H₁₀LiN

: 1394958-96-3
1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

Guidance literature:: {6,9-dimethoxy-3,12-dioxo-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane; C₁₄H₁₀LiN; Inert atmosphere; Schlenk technique;

Acidic conditions; Inert atmosphere; Schlenk technique;
DOI:10.1002/chem.201303169

Reference yield:

: 1394958-94-1
{12-hydroxy-3,6,9-trimethoxy-6,9-diphenyl-14-[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-1-yl}tris(propan-2-yl)silane

: 1394958-96-3
1-(4-{3,12-dihydroxy-12-[4-(1H-indol-1-yl)phenyl]-6,9-dimethoxy-6,9-diphenyl-1,14-bis[tris(propan-2-yl)silyl]tetradeca-1,4,7,10,13-pentayn-3-yl}phenyl)-1H-indole

Guidance literature:: Multi-step reaction with 2 steps

1.1: manganese(IV) oxide / dichloromethane / 3 h / 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - -10 °C / Inert atmosphere

2.2: 3 h / -10 °C / Inert atmosphere

With manganese(IV) oxide; n-butyllithium; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c2cc34176j