thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Base Information

Chemical Name:thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester
CAS No.:637741-59-4
Molecular Formula:C₄₇H₅₆O₈SSi
Molecular Weight:809.108
Hs Code.:

thioacetic acid <i>S</i>-[4-(<i>tert</i>-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Synonyms:thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Suppliers and Price of thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

There total 6 articles about thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 637741-58-3
Methanesulfonic acid (1S,2S,3R)-4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl ester

: 10387-40-3
potassium thioacetate

: 637741-59-4
thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Guidance literature:: In N,N-dimethyl-formamide; toluene; for 11h; Heating;
DOI:10.1039/b305818b

Reference yield:

: 4-Nitro-benzoic acid (1S,2S,3R)-4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl ester

: 637741-59-4
thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Guidance literature:: Multi-step reaction with 3 steps

1: 2.67 g / diisobutylaluminum hydride / CH₂Cl₂; hexane / 4 h / -78 °C

2: triethylamine / CH₂Cl₂ / 1 h / 0 °C

3: 56 percent / toluene; dimethylformamide / 11 h / Heating

With diisobutylaluminium hydride; triethylamine; In hexane; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1039/b305818b

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 637741-59-4
thioacetic acid S-[4-(tert-butyl-diphenyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl] ester

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / imidazole / dimethylformamide / 3 h / 20 °C

2: diisopropyl azodicarboxylate; triphenylphosphine / tetrahydrofuran / 4 h / 20 °C

3: 2.67 g / diisobutylaluminum hydride / CH₂Cl₂; hexane / 4 h / -78 °C

4: triethylamine / CH₂Cl₂ / 1 h / 0 °C

5: 56 percent / toluene; dimethylformamide / 11 h / Heating

With 1H-imidazole; di-isopropyl azodicarboxylate; diisobutylaluminium hydride; triethylamine; triphenylphosphine; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene; 2: Mitsunobu reaction;
DOI:10.1039/b305818b