benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Base Information

Chemical Name:benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside
CAS No.:113308-80-8
Molecular Formula:C₂₂H₃₄O₅Si
Molecular Weight:406.594
Hs Code.:

Synonyms:benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Suppliers and Price of benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

There total 6 articles about benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 113308-88-6
benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

: 113308-80-8
benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Guidance literature:: With benzenesulfonyl chloride; In pyridine; at 40 - 50 ℃;

Reference yield:

: 79974-79-1
benzyl 2,3-anhydro-β-L-erythropentopyranosid-4-ulose

: 113308-80-8
benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / NaI, NaOAc*3H₂O / acetic acid; acetone / 2.5 h

2: 76 percent / imidazole / dimethylformamide / 6 h / Ambient temperature

3: 1.) BuLi, diisopropylamine / 1.) hexane, THF, 1 h, 2.) THF, overnight

4: 85 percent / benzenesulfonyl chloride / pyridine / 40 - 50 °C

With 1H-imidazole; n-butyllithium; sodium acetate; diisopropylamine; benzenesulfonyl chloride; sodium iodide; In pyridine; acetic acid; N,N-dimethyl-formamide; acetone;

Reference yield:

: 113308-87-5
benzyl 3-deoxy-β-L-glycero-pentopyranosid-4-ulose

: 113308-80-8
benzyl 2-O-(tert-butyldimethylsilyl)-4-C-(2-carboxypropan-2-yl)-3-deoxy-α-D-threo-pentopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / imidazole / dimethylformamide / 6 h / Ambient temperature

2: 1.) BuLi, diisopropylamine / 1.) hexane, THF, 1 h, 2.) THF, overnight

3: 85 percent / benzenesulfonyl chloride / pyridine / 40 - 50 °C

With 1H-imidazole; n-butyllithium; diisopropylamine; benzenesulfonyl chloride; In pyridine; N,N-dimethyl-formamide;