benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

Base Information

Chemical Name:benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose
CAS No.:113308-79-5
Molecular Formula:C₁₈H₂₈O₄Si
Molecular Weight:336.503
Hs Code.:

Synonyms:benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

Suppliers and Price of benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

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Technology Process of benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

There total 3 articles about benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 113308-87-5
benzyl 3-deoxy-β-L-glycero-pentopyranosid-4-ulose

: 18162-48-6
tert-butyldimethylsilyl chloride

: 113308-79-5
benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; for 6h; Ambient temperature;

Reference yield:

: 79974-79-1
benzyl 2,3-anhydro-β-L-erythropentopyranosid-4-ulose

: 113308-79-5
benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / NaI, NaOAc*3H₂O / acetic acid; acetone / 2.5 h

2: 76 percent / imidazole / dimethylformamide / 6 h / Ambient temperature

With 1H-imidazole; sodium acetate; sodium iodide; In acetic acid; N,N-dimethyl-formamide; acetone;

Reference yield:

: 65359-87-7
benzyl 2,3-anhydro-β-L-ribopyranoside

: 113308-79-5
benzyl 2-O-(tert-butylsimethylsilyl)-3-deoxy-β-L-glycero-pentopyranosid-4-ulose

Guidance literature:: Multi-step reaction with 3 steps

1: (COCl)2, NEt₃ / dimethylsulfoxide

2: NaI, HOAc, NaOAc / acetone

3: imidazol

With 1H-imidazole; oxalyl dichloride; sodium acetate; acetic acid; triethylamine; sodium iodide; In dimethyl sulfoxide; acetone;
DOI:10.1016/S0040-4039(00)96200-2