7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Base Information

Chemical Name:7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide
CAS No.:131393-02-7
Molecular Formula:C₃₁H₃₆O₃P*I
Molecular Weight:614.503
Hs Code.:

Synonyms:7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Suppliers and Price of 7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

There total 8 articles about 7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 131393-01-6
1-(7-iodohept-4Z-enyl)-4-methyl-2,6,7-trioxabicyclo<2.2.2>octane

: 603-35-0
triphenylphosphine

: 131393-02-7
7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Guidance literature:: With potassium carbonate; In acetonitrile; at 45 ℃; for 72h;

Reference yield:

: 3143-02-0
3-hydroxymethyl-3-methyloxethane

: 131393-02-7
7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Guidance literature:: Multi-step reaction with 8 steps

1: 87.5 percent / dicyclohexylcarbodiimide, 4-dimethylaminopyridine / CH₂Cl₂ / 1. 5 min, 0 deg C 2. 5.5 h, room temperature

2: 80 percent / BF₃*Et₂O / CH₂Cl₂ / 1. -10 deg C to 0 deg C, 2 h 2. 0 deg C, 7 h

3: 81 percent / tetrahydrofuran; dimethylformamide; paraffin; xylene / 20 h / 1. -80 deg C to -75 deg C, 90 min, 2. to room temperature, 2 h 3. room temperature

4: 1. n-butyllithium / 1. DME, hexane, -78 deg C, 75 min 2. 10 deg C, 23 h

5: 92 percent / H₂ / NaBH₄, Ni(Ac)2*4H₂O, ethylene diamine / ethanol / 2 h

6: 73 percent / NEt₃ / diethyl ether / 0 °C

7: 86 percent / NaI, K₂CO₃ / acetone / 168 h / 35 °C

8: 76 percent / K₂CO₃ / acetonitrile / 72 h / 45 °C

With dmap; n-butyllithium; hydrogen; potassium carbonate; triethylamine; dicyclohexyl-carbodiimide; sodium iodide; sodium tetrahydroborate; boron trifluoride diethyl etherate; nickel diacetate; ethylenediamine; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; N,N-dimethyl-formamide; acetone; acetonitrile; paraffin; xylene;

Reference yield:

: 89276-36-8
1-(3-bromopropyl)-4-methyl-2,6,7-trioxabicyclo[2,2,2]octane

: 131393-02-7
7-(2,6,7-trioxabicyclo<2.2.2>octyl)-hept-3Z-enyl triphenylphosphonium iodide

Guidance literature:: Multi-step reaction with 6 steps

1: 81 percent / tetrahydrofuran; dimethylformamide; paraffin; xylene / 20 h / 1. -80 deg C to -75 deg C, 90 min, 2. to room temperature, 2 h 3. room temperature

2: 1. n-butyllithium / 1. DME, hexane, -78 deg C, 75 min 2. 10 deg C, 23 h

3: 92 percent / H₂ / NaBH₄, Ni(Ac)2*4H₂O, ethylene diamine / ethanol / 2 h

4: 73 percent / NEt₃ / diethyl ether / 0 °C

5: 86 percent / NaI, K₂CO₃ / acetone / 168 h / 35 °C

6: 76 percent / K₂CO₃ / acetonitrile / 72 h / 45 °C

With n-butyllithium; hydrogen; potassium carbonate; triethylamine; sodium iodide; sodium tetrahydroborate; nickel diacetate; ethylenediamine; In tetrahydrofuran; diethyl ether; ethanol; N,N-dimethyl-formamide; acetone; acetonitrile; paraffin; xylene;