Cupric perchlorate

Base Information

• Chemical Name: Cupric perchlorate
• CAS No.: 13770-18-8
• Molecular Formula: ClH O4 . 1/2 Cu
• Molecular Weight: 262.45
• European Community (EC) Number: 237-391-4
• UNII: IBE83VVE7T
• DSSTox Substance ID: DTXSID40890720
• Nikkaji Number: J43.806E
• Wikipedia: Copper(II)_perchlorate
• Wikidata: Q15628157
• Mol file: 13770-18-8.mol

Synonyms:copper(2+) perchlorate hexahydrate;copper(II) perchlorate;copper(II) perchlorate dihydrate

Chemical Property of Cupric perchlorate

Chemical Property:

• Melting Point: about 230-240°
• PSA: 148.54000
• Density: 2.22
• LogP: 0.42610
• Water Solubility.: soluble H2O, ether, dioxane, ethyl acetate; insoluble benzene, CCl4 [MER06]; g/100g solution H2O: 54.3 (0°C), 59.3 (30°C); solid phase, Cu(ClO4)2 ·6H2O [KRU93]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 260.826619
• Heavy Atom Count: 11
• Complexity: 95.8

Purity/Quality:

98% ^*data from raw suppliers

CUPRICPERCHLORATE,DEHYD ^*data from reagent suppliers

Safty Information:

• Pictogram(s): OXi
• Hazard Codes: O:Oxidizing;;
• Statements: R36/37/38:Irritating to eyes, respiratory system and skin.; R8:Contact with combustible material may cause fire.
• Safety Statements: S17:Keep away from combustible material.; S26:In case of contact with eyes, rinse immediately with plenty of water and se

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Perchlorates
• Canonical SMILES: [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Cu+2]

Refernces

Assembly of a series of MOFs based on the 2-(m-methoxyphenyl)imidazole dicarboxylate ligand

10.1039/c2dt32727a

This research details the synthesis and characterization of a series of metal-organic frameworks (MOFs) based on the 2-(m-methoxyphenyl)imidazole dicarboxylate ligand, m-H3MOPhIDC. The purpose of the study was to explore the coordination features of the imidazole dicarboxylate ligand and its influence on the assembly of MOFs with potential applications in gas storage, catalysis, and more. The researchers successfully synthesized seven coordination polymers with diverse structures ranging from one-dimensional chains to three-dimensional frameworks by controlling synthetic conditions such as solvent and pH values. The chemicals used in the process included the ligand m-H3MOPhIDC, various metal salts (Sr(NO3)2, Cd(NO3)2·4H2O, Cu(ClO4)2, and CoCl2·6H2O), auxiliary ligands (1,10-phenanthroline and 2,2'-bipyridine), and Et3N as a base. The conclusions highlighted the significant impact of reaction conditions, core metal ions, and auxiliary ligands on the structures of the resulting MOFs, and confirmed the versatility of the m-H3MOPhIDC ligand in constructing novel MOFs with interesting structures and properties.

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