Nickelate(4-), ((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonato))(6-)-N(sup 21),N(sup 22),N(sup 23),N(sup 24))-, tetrasodium, (SP-4-1)-

Base Information

• Chemical Name: Nickelate(4-), ((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonato))(6-)-N(sup 21),N(sup 22),N(sup 23),N(sup 24))-, tetrasodium, (SP-4-1)-
• CAS No.: 67204-04-0
• Molecular Formula: C44H24 N4 Ni O12 S4 . 4 Na
• Molecular Weight: 1079.5934
• DSSTox Substance ID: DTXSID401333927
• Mol file: 67204-04-0.mol

Synonyms:67204-04-0;Nickelate(4-), ((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonato))(6-)-N(sup 21),N(sup 22),N(sup 23),N(sup 24))-, tetrasodium, (SP-4-1)-;C44H24N4NiO12S4.4Na;DTXSID401333927;LS-96289;C44-H24-N4-Ni-O12-S4.4Na

Chemical Property of Nickelate(4-), ((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonato))(6-)-N(sup 21),N(sup 22),N(sup 23),N(sup 24))-, tetrasodium, (SP-4-1)-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 16
• Rotatable Bond Count: 4
• Exact Mass: 1077.921776
• Heavy Atom Count: 69
• Complexity: 1670

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1C2=C3C=CC(=C(C4=CC=C([N-]4)C(=C5C=CC(=N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)S(=O)(=O)[O-])C8=CC=C(C=C8)S(=O)(=O)[O-])C9=CC=C(C=C9)S(=O)(=O)[O-])[N-]3)S(=O)(=O)[O-].[Na+].[Na+].[Na+].[Na+].[Ni+2]

Technology Process of Nickelate(4-), ((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonato))(6-)-N(sup 21),N(sup 22),N(sup 23),N(sup 24))-, tetrasodium, (SP-4-1)-

There total 3 articles about Nickelate(4-), ((4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis(benzenesulfonato))(6-)-N(sup 21),N(sup 22),N(sup 23),N(sup 24))-, tetrasodium, (SP-4-1)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.3%

nickel(II) oxide (1313-99-1) + tetrakis(sulphonatophenyl)porphyrin (39050-26-5) → nickel(II)-tetrakis(p-(sodiosulfonato)phenyl)porphyrin (67204-04-0)

Guidance literature:

In water; for 24h; Reflux;

DOI:10.1016/j.saa.2014.07.053

Reference yield:

nickel(II) (14701-22-5) + tetrakis(sulphonatophenyl)porphyrin (39050-26-5) → nickel(II)-tetrakis(p-(sodiosulfonato)phenyl)porphyrin (67204-04-0)

Guidance literature:

In ethanol; for 0.5h; Reflux;

DOI:10.14233/ajchem.2022.23463

Reference yield:

nickel(II)-tetrakis(p-(ammoniosulfonato)phenyl)porphyrin → nickel(II)-tetrakis(p-(sodiosulfonato)phenyl)porphyrin (67204-04-0)

Guidance literature:

passage through a column of Amberlite CG 120, 100-200 mesh, sodium form;

upstream raw materials:

nickel(II) oxide

tetrakis(sulphonatophenyl)porphyrin

nickel(II)

Downstream raw materials:

nickel-tetrakis(p-(sodiosulfonato)phenyl)porphyrin⁽¹⁺⁾

nickel-tetrakis(p-(sodiosulfonato)phenyl)porphyrin⁽²⁺⁾

nickel-tetrakis(p-(sodiosulfonato)phenyl)porphyrin^(1-)

nickel-tetrakis(p-(sodiosulfonato)phenyl)porphyrin^(2-)