[Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

Base Information

Chemical Name:[Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]
CAS No.:1384282-07-8
Molecular Formula:C₅₂H₆₇N₅O₄Zn
Molecular Weight:891.525
Hs Code.:

Synonyms:[Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

Suppliers and Price of [Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

There total 2 articles about [Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1384282-05-6
5-(4′-bromophenyl)-2,3,7,8,12,18-hexamethyl-13,17-di-n-pentylporphyrin zinc(II)

: 66943-05-3
1,4,7,10-tetraoxa-15-azacyclopentadecane

: 1384282-07-8
[Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

Guidance literature:: With 2-dicyclohexylphosphino-2'-(dimethylamino)biphenyl; Pd(C₆H₅C₂H₂C(O)C₂H₂C₆H₅)2; sodium tert-butoxide; In 1,4-dioxane; under Ar, ratio biphenyl/Pd 2/1; biphenyl deriv., Pd and Na compds. placed in flask, added soln. of crown ether via syringe, added Zn compd., purged with Ar for 3 min, sealed, heated at 100°C for 27 h with stirring, cooled to room temp.; added dichloromethane, filtered, concd. (vac.), purified by column chromy. (silica gel, CH2Cl2/CH3OH);
DOI:10.1039/c2dt30123g

Reference yield:

: 5-(4-bromophenyl)-3,7,12,13,17,18-hexamethyl-2,8-(dipentyl)porphyrin

: 1384282-07-8
[Zn(5-(4'-(1,4,7,10-tetraoxa-13-aza-cyclopentadec-13-yl)phenyl)-2,3,7,8,12,18-hexamethyl-13,17-dipentylporphyrinate)]

Guidance literature:: Multi-step reaction with 2 steps

1: zinc diacetate / chloroform / 20 °C

2: bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; DavePhos / 1,4-dioxane / 27 h / 100 °C / Inert atmosphere

With zinc diacetate; bis(dibenzylideneacetone)-palladium⁽⁰⁾; sodium t-butanolate; DavePhos; In 1,4-dioxane; chloroform;
DOI:10.1039/c2dt30123g