2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II)

Base Information

• Chemical Name: 2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II)
• CAS No.: 620966-84-9
• Molecular Formula: C₂₂H₈F₁₀N₂PtS₂
• Molecular Weight: 749.515
• Mol file: 620966-84-9.mol

Synonyms:2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II)

Chemical Property of 2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II)

There total 1 articles about 2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dichloro(2,2'-bipyridine)platinum(II) (13965-31-6) + pentafluorophenylthiol (771-62-0) → 2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II) (620966-84-9)

Guidance literature:

With potassium tert-butylate; In acetone; for 5h; Inert atmosphere;

DOI:10.1016/j.ica.2014.07.058

Reference yield:

2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II) (620966-84-9) → Pt(NC5H4C5H4N)(SC6F5)2(1-)

Guidance literature:

With n-Bu₄NBF₄; In N,N-dimethyl-formamide; Electrochem. Process; Pt complex in DMF contg. n-Bu4NBF4 electrochemically reduced; not isolated; monitored by UV-vis spectra;

DOI:10.1021/ic026286l

Reference yield:

2,2'-bipyridinebis(pentafluorophenylthiolato)platinum(II) (620966-84-9) → Pt(NC5H4C5H4N)(SC6F5)2(2-)

Guidance literature:

With n-Bu₄NBF₄; In N,N-dimethyl-formamide; Electrochem. Process; Pt complex in DMF contg. n-Bu4NBF4 electrochemically reduced at 223 K; applied potential -1.98 V vs SCE; not isolated; monitored by UV-vis spectra;

DOI:10.1021/ic026286l

upstream raw materials:

dichloro(2,2'-bipyridine)platinum(II)

pentafluorophenylthiol