(2,2'-Bipyridine)dichloroplatinum(II)

Base Information

• Chemical Name: (2,2'-Bipyridine)dichloroplatinum(II)
• CAS No.: 13965-31-6
• Molecular Formula: C10H8 Cl2 N2 Pt
• Molecular Weight: 422.173
• European Community (EC) Number: 623-705-0
• DSSTox Substance ID: DTXSID40422000
• Mol file: 13965-31-6.mol

Synonyms:13965-31-6;(2,2'-Bipyridine)dichloroplatinum(II);2,2'-Bipyridinedichloroplatinum;dichloroplatinum;2-pyridin-2-ylpyridine;(2,2/'-BIPYRIDINE)DICHLOROPLATINUM(II);SCHEMBL1278984;DTXSID40422000;Platinum, (2,2'-bipyridine)dichloro-;(2,2'-bipyridine)dichloro-platinum(ii);(2,2'-Bipyridine)dichloroplatinum(II), 96%;F74395;Platinum, (2,2'-bipyridine-N,N')dichloro-, (SP-4-2)-

Chemical Property of (2,2'-Bipyridine)dichloroplatinum(II)

Chemical Property:

• Melting Point: >300 °C(lit.)
• PSA: 25.78000
• LogP: 3.52010
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 420.971248
• Heavy Atom Count: 15
• Complexity: 123

Purity/Quality:

98%,99%, ^*data from raw suppliers

(2,2′-Bipyridine)dichloroplatinum(II) 96% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.Cl[Pt]Cl

Technology Process of (2,2'-Bipyridine)dichloroplatinum(II)

There total 60 articles about (2,2'-Bipyridine)dichloroplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[2,2]bipyridinyl (366-18-7) + potassium tetrachloroplatinate(II) (10025-99-7) → dichloro(2,2'-bipyridine)platinum(II) (13965-31-6)

Guidance literature:

With HCl; In hydrogenchloride; mixing of hot solns., stiring and heating 30 min (pptn.); filtration, washing (hot water, EtOH), drying (vac.); elem. anal.;

Reference yield: 95.0%

hydrogenchloride (7647-01-0,15364-23-5) + [2,2]bipyridinyl (366-18-7) + potassium tetrachloroplatinate(II) (10025-99-7) → dichloro(2,2'-bipyridine)platinum(II) (13965-31-6)

Guidance literature:

In water;

DOI:10.1246/bcsj.71.1363

Reference yield: 91.0%

potassium tetrachloroplatinate(II) (10025-99-7) → dichloro(2,2'-bipyridine)platinum(II) (13965-31-6)

Guidance literature:

With [2,2]bipyridinyl; In hydrogenchloride; K2PtCl4 in hot water heated for 1 h with 2,2'-bipyridyl in aq. HCl; elem.anal.;

DOI:10.1016/S0277-5387(00)81635-6

upstream raw materials:

[2,2]bipyridinyl

potassium tetrachloroplatinate(II)

hydrogenchloride

tetrachloro(2,2'-bipyridine)platinum(IV)

Downstream raw materials:

bis(N,N-diethyldithiocarbamate)platinum(II)

{Pt(C₁₀H₈N₂)(NH₂C₂H₅)Cl}⁽¹⁺⁾*B(C₆H₅)4^(1-)={Pt(C₁₀H₈N₂)(NH₂C₂H₅)Cl}B(C₆H₅)4

Pt(CH₃C₈H₄N₂NCH₂C₆H₅)(C₁₀H₈N₂)(H₂O)⁽¹⁺⁾*ClO₄^(1-)=[Pt(CH₃C₈H₄N₂NCH₂C₆H₅)(C₁₀H₈N₂)(H₂O)]ClO₄

[Pt(1,2-bis(benzylthio)ethylene-1,2-dithiolate)(2,2'-bipyridine)]

Refernces

• 1、 La Manna, Sara,Florio, Daniele,Iacobucci, Ilaria,Napolitano, Fabiana,De Benedictis, Ilaria,Malfitano, Anna Maria,Monti, Maria,Ravera, Mauro,Gabano, Elisabetta,Marasco, Daniela. "A comparative study of the effects of platinum (Ii) complexes on β-amyloid aggregation: Potential neurodrug applications". . p. 1 - 13. Retrieved 2021/03/18.
• 2、 Zhao, Xiaowei,Zhang, Yamei,Hou, Xiaonan,Shi, Jianhong,Shen, Shigang,Huo, Shuying. "Synthesis, characterization, and cytotoxicity of Pt(IV) complexes containing 1,10-phenanthroline and 2,2′-bipyridine and diaminocyclohexane ligands". . p. 219 - 228. Retrieved 2017/03/16.