{(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

Base Information

Chemical Name:{(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol
CAS No.:488113-86-6
Molecular Formula:C₂₁H₂₈O₃Si
Molecular Weight:356.537
Hs Code.:

Synonyms:{(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

Suppliers and Price of {(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of {(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of {(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

There total 11 articles about {(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 79568-67-5
(Z)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)pent-2-en-1-ol

: 488113-86-6
{(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; Diethyl tartrate; In dichloromethane; at -20 ℃;
DOI:10.1021/jo00338a046

Reference yield: 80.0%

: 127665-77-4
(E)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)pent-2-en-1-ol

: 488113-86-6
{(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

Guidance literature:: With tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate; titanium(IV)isopropoxide; In dichloromethane; at -30 ℃; for 8h;
DOI:10.1016/j.tetlet.2012.11.015

Reference yield:

: 79568-67-5
(Z)-5-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)pent-2-en-1-ol

: 488113-86-6
{(2R,3S)-3-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-oxiranyl}-methanol

: 256494-27-6
(2S,3R)-(3-(2-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)ethyl)-2-oxiranyl)methan-1-ol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; 4 A molecular sieve; In decane; dichloromethane; at -20 ℃; for 24h; Title compound not separated from byproducts;
DOI:10.1021/ja060064v