CID 6101206

Base Information

Chemical Name:CID 6101206
CAS No.:13146-23-1
Molecular Formula:C8H5 Cu
Molecular Weight:164.674
Hs Code.:2902909090
DSSTox Substance ID:DTXSID40927207
Mol file:13146-23-1.mol

Synonyms:13146-23-1;Copper (I) phenylacetylide;DTXSID40927207;SFLVZUJLUPAJNE-UHFFFAOYSA-N;Copper(1+) 2-phenylethyn-1-ide

Suppliers and Price of CID 6101206

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
Copper(I) phenylacetylide, min. 97%
1g
$ 90.00

Strem Chemicals
Copper(I) phenylacetylide, min. 97%
5g
$ 360.00

Alfa Aesar
Copper(I) phenylacetylide
2g
$ 146.00

Total 14 raw suppliers

Chemical Property of CID 6101206

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:g/cm³
LogP:1.54240
Sensitive.:Air & Moisture Sensitive
Water Solubility.:Soluble in acetone and acetonitrile. Insoluble in water
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:163.968722
Heavy Atom Count:9
Complexity:98.5

Purity/Quality:

98%Min ^*data from raw suppliers

Copper(I) phenylacetylide, min. 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 20/21/22
Safety Statements: 22-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[C-]#CC1=CC=CC=C1.[Cu+]
Uses Copper(I) phenylacetylide participates in efficient coupling with a range of aryl iodides and bromides to give substituted tolanes?which, if possessing an?ortho?amino or hydroxy group, can be thermolyzed to yield 2-phenylbenzofurans, -indoles, and -furo[3,2-b]pyridines.

Technology Process of CID 6101206

There total 48 articles about CID 6101206 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.2%

: 12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8
copper

: 536-74-3
phenylacetylene

: 13146-23-1
copper(I) phenylacetylide

Guidance literature:: With tetraethylammonium bromide; In acetonitrile; byproducts: H2; Electrolysis; electrolysis conducted at room temp., controlled potential -2.4V, electrolyte soln.: 0.76 M PhC2H and 0.12 Et4NBr in CH3CN, pptn.; ppt. filtered, washed with hot CH3CN, dried (room temp., under N2);

Reference yield: 97.0%

: 12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8
copper

: 536-74-3
phenylacetylene

: 13146-23-1
copper(I) phenylacetylenide

Guidance literature:: With Et₄N(CH₃C₆H₄SO₃); In acetonitrile; at 20 ℃; for 4h; Reagent/catalyst; Electrochemical reaction;
DOI:10.1039/c9ra06782e