13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine

Base Information

• Chemical Name: 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine
• CAS No.: 1361126-04-6
• Molecular Formula: C₂₇H₂₂N₂
• Molecular Weight: 374.485
• Mol file: 1361126-04-6.mol

Synonyms:13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine

Chemical Property of 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine

There total 14 articles about 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

N-(2-chlorophenyl)-9,9-dimethyl-10-phenyl-9,10-dihydroacridin-2-amine (1361126-03-5) → 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine (1361126-04-6)

Guidance literature:

With di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; caesium carbonate; palladium diacetate; In ISOPROPYLAMIDE; at 190 ℃; for 4h;

Reference yield: 48.0%

→ 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine (1361126-04-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; In N,N-dimethyl-formamide; at 150 ℃; for 24h;

Reference yield:

9,9-dimethyl-10-phenyl-9,10-dihydroacridine → 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine (1361126-04-6)

Guidance literature:

Multi-step reaction with 3 steps

1: N-Bromosuccinimide / N,N-dimethyl-formamide / 6 h / 0 °C

2: caesium carbonate; tri-tert-butyl phosphine / palladium diacetate / toluene / 4 h / 120 °C

3: caesium carbonate; di-tert-butyl(methyl)phosphonium tetrafluoroborate salt / palladium diacetate / ISOPROPYLAMIDE / 4 h / 190 °C

With N-Bromosuccinimide; tri-tert-butyl phosphine; di-tert-butyl(methyl)phosphonium tetrafluoroborate salt; caesium carbonate; palladium diacetate; In ISOPROPYLAMIDE; N,N-dimethyl-formamide; toluene;

upstream raw materials:

9,9‐dimethyl‐10H‐acridine

α,α-Dimethyl-2-(phenylamino)benzolmethanol

2-(phenylamino)benzoic acid

Methyl N-phenylanthranilate

Downstream raw materials:

C₃₃H₂₇BN₂O₂

C₄₉H₃₆N₄

Refernces

• 1、 -. "Deuterated organic compounds for organic light-emitting diode and organic light-emitting diode including the same". . . Retrieved 2020/12/15.
• 2、 -. "NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME". . . Retrieved 2012/04/10.