4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

Base Information

Chemical Name:4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate
CAS No.:1450608-97-5
Molecular Formula:C₁₆H₁₇NO₈
Molecular Weight:351.313
Hs Code.:

Synonyms:4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

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Chemical Property of 4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

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Technology Process of 4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

There total 4 articles about 4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1450608-85-1
C₉H₁₄O₄

: 7693-46-1
4-Nitrophenyl chloroformate

: 1450608-97-5
4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

Guidance literature:: With pyridine; In dichloromethane; at 0 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/jm400768f

Reference yield:

: octahydro-2H-furo[3′,2′:4,5]furo[2,3-c]pyran-4-ol

: 1450608-97-5
4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

Guidance literature:: Multi-step reaction with 2 steps

1: lipase amano PS-30 / tetrahydrofuran / 20 h / 23 °C / Inert atmosphere

2: pyridine / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere

With pyridine; lipase amano PS-30; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jm400768f

Reference yield:

: 3,3a,7,8a-tetrahydro-2H-furo[3′,2′:4,5]furo[2,3-c]pyran-4(5H)-one

: 1450608-97-5
4-nitrophenyl ((3aR,3bR,4R,7aS,8aS)-octahydro-5H-furo-[3′,2′:4,5]furo[2,3-c]pyran-4-yl)carbonate

Guidance literature:: Multi-step reaction with 4 steps

1: palladium 10% on activated carbon; hydrogen / methanol / 12 h / 760.05 Torr / Inert atmosphere

2: L-Selectride / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

3: lipase amano PS-30 / tetrahydrofuran / 20 h / 23 °C / Inert atmosphere

4: pyridine / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere

With pyridine; palladium 10% on activated carbon; lipase amano PS-30; hydrogen; L-Selectride; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jm400768f