CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&

Base Information

Chemical Name:CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&
CAS No.:12278-58-9
Molecular Formula:C₂₅H₂₃ClPRh
Molecular Weight:492.79
Hs Code.:

Synonyms:Rhodium,chloro(2,5-norbornadiene)(triphenylphosphine)- (6CI,8CI); Bicyclo[2.2.1]hepta-2,5-diene,rhodium complex; Chloro(norbornadiene)(triphenylphosphine)rhodium

Suppliers and Price of CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&

Chemical Property:

PSA：13.59000
LogP:5.12310

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of CHLORONORBORNADIENETRIPHENYLPHOSPHINERH&

There total 1 articles about CHLORONORBORNADIENETRIPHENYLPHOSPHINERH& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 12257-42-0
[(norbornadiene)rhodium(I)chloride]2

: 603-35-0
triphenylphosphine

: 12278-58-9
(η4-bicyclo{2.2.1}hepta-2,5-diene)RhCl(P(C6H5)3)

Guidance literature:: In tetrahydrofuran; under protective gas; room temp.;
DOI:10.1246/bcsj.73.129

Reference yield: 75.0%

: 12278-58-9
(η4-bicyclo{2.2.1}hepta-2,5-diene)RhCl(P(C6H5)3)

: Natrium-<3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)>pyrrolat

: 124273-50-3
(η4-bicyclo{2.2.1}hepta-2,5-diene){3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethyl-furan-2-yl-methyl)pyrrolato-N}(triphenylphosphine)rhodium(I)

Guidance literature:: In tetrahydrofuran; slowly addn. soln. of Rh-complex in THF to suspn. of difurfurylpyrrolate in THF (20°C); stirring (30 min);; removal of solvent (vac:) dissoln. in CH2Cl2; filtn.; addn. hexane; removal of solvent; elem. anal.;

Reference yield:

: 12278-58-9
(η4-bicyclo{2.2.1}hepta-2,5-diene)RhCl(P(C6H5)3)

: Natrium-<3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)>pyrrolat

: 124273-54-7
dicarbonyl{3,4-diethoxycarbonyl-2,5-bis(4-ethoxycarbonyl-3,5-dimethylfuran-2-yl-methyl)pyrrolato-N}(triphenylphosphine)-rhodium(I)

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: CO / dichloromethane

With CO; In tetrahydrofuran; dichloromethane;