3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II))

Base Information

• Chemical Name: 3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II))
• CAS No.: 819793-52-7
• Molecular Formula: C₉₆H₇₀N₈Ni₂
• Molecular Weight: 1453.05
• Mol file: 819793-52-7.mol

Synonyms:3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II))

Chemical Property of 3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II))

There total 1 articles about 3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrin) + nickel diacetate (373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6) → 3,3'-bis(meso-tetra(p-tolyl)-2-aza-21-carbaporphyrinatonickel(II)) (819793-52-7)

Guidance literature:

In N,N-dimethyl-formamide; toluene; to soln. of porhyrin in toluene soln. of Ni acetate in DMF added, mixt. heated at reflux under N2 for 1 h; solvents removed, residue purified by chromy. (silica gel), first green band eluted with CH2Cl2 collected, recrystd. from hexane under N2; elem.anal.;

DOI:10.1002/anie.200461361

Reference yield:

3,3'-bis(meso-p-tolyl-2-aza-21-carbaporphyrinatonickel(II)) (819793-52-7) + methyl iodide (74-88-4) → [(Ni(C20H6N4(CH3)(C6H4(CH3))4))(Ni(C20H6N4(CH3)2(C6H4(CH3))4))] + [Ni(C20H6N4(CH3)(C6H4(CH3))4)]2 (1353713-33-3) + [Ni(C20H6N4(CH3)(C6H4(CH3))4)]2 (1353713-32-2) + [Ni(C20H6N4(CH3)(C6H4(CH3))4)]2*2CH2Cl2

Guidance literature:

In dichloromethane; under N2 atm.; react. of Ni complex with MeI in boiling CH2Cl2 in presence of K2CO3/dibenzo-18-crown-6 ether system; isolated by HPLC; detd. by cyclic voltammetry;

DOI:10.1039/c1cc14536c

upstream raw materials:

nickel diacetate

Downstream raw materials:

[Ni(C₂₀H₆N₄(CH₃)(C₆H₄(CH₃))4)]2

[Ni(C₂₀H₆N₄(CH₃)(C₆H₄(CH₃))4)]2