methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

Base Information

Chemical Name:methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate
CAS No.:1573112-29-4
Molecular Formula:C₂₁H₂₀BrNO₂
Molecular Weight:398.299
Hs Code.:

Synonyms:methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

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Chemical Property of methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

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Technology Process of methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

There total 6 articles about methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 875-79-6
1,2-dimethylindole

: 272456-69-6
(E)-methyl 2-diazo-4-(4-bromophenyl)but-3-enoate

: 1573112-29-4
methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

Guidance literature:: With Rh₂[(N-(4-dodecylphenyl)sulfonyl)-(S)-prolinate]4; In toluene; at -45 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tetlet.2013.11.065

Reference yield:

: 103-84-4
Acetanilid

: 1573112-29-4
methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver hexafluoroantimonate; copper diacetate; silver carbonate / 1,4-dioxane / 24 h / 110 °C / Inert atmosphere

2: potassium hydroxide / tetrahydrofuran; ethanol / Reflux

3: sodium hydride / tetrahydrofuran

4: Rh₂[(N-(4-dodecylphenyl)sulfonyl)-(S)-prolinate]4 / toluene / -45 - 20 °C / Inert atmosphere

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; Rh₂[(N-(4-dodecylphenyl)sulfonyl)-(S)-prolinate]4; copper diacetate; sodium hydride; silver carbonate; potassium hydroxide; In tetrahydrofuran; 1,4-dioxane; ethanol; toluene;
DOI:10.1016/j.tetlet.2013.11.065

Reference yield:

: 169214-12-4
[2'-²H]acetanilide

: 1573112-29-4
methyl 3-(4-bromophenyl)-3a,4-dimethyl-3,3a,4,8b-tetrahydrocyclopenta[b]indole-1-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver hexafluoroantimonate; copper diacetate; silver carbonate / 1,4-dioxane / 1 h / 110 °C / Schlenk technique; Inert atmosphere

2: potassium hydroxide / tetrahydrofuran; ethanol / Reflux

3: sodium hydride / tetrahydrofuran

4: Rh₂[(N-(4-dodecylphenyl)sulfonyl)-(S)-prolinate]4 / toluene / -45 - 20 °C / Inert atmosphere

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; Rh₂[(N-(4-dodecylphenyl)sulfonyl)-(S)-prolinate]4; copper diacetate; sodium hydride; silver carbonate; potassium hydroxide; In tetrahydrofuran; 1,4-dioxane; ethanol; toluene;
DOI:10.1016/j.tetlet.2013.11.065