METHALLYLNICKEL CHLORIDE DIMER

Base Information

• Chemical Name: METHALLYLNICKEL CHLORIDE DIMER
• CAS No.: 12145-60-7
• Molecular Formula: C8H14 Cl2 Ni2
• Molecular Weight: 298.49
• Mol file: 12145-60-7.mol

Synonyms:Nickel,di-m-chlorobis(2-methyl-p-allyl)di- (8CI); Nickel, di-m-chlorobis[(1,2,3-h)-2-methyl-2-propenyl]di- (9CI);Nickel, dichlorobis(2-methyl-p-allyl)di- (7CI); (Methallyl)nickel choride dimer;Dichlorobis(2-methylallyl)dinickel; p-Methallylnickel chloride

Chemical Property of METHALLYLNICKEL CHLORIDE DIMER

Chemical Property:

• PSA: 0.00000
• LogP: 4.43920
• Sensitive.: air sensitive, moisture sensitiv

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methallylnickel chloride dimer ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R20/21/22-42/43-45:
• Hazard Codes: R20/21/22-42/43-45:
• Statements: 20/21/22-42/43-45
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHALLYLNICKEL CHLORIDE DIMER

There total 1 articles about METHALLYLNICKEL CHLORIDE DIMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + 3-Chloro-2-methylpropene (563-47-3) → {(η3-2-methylallyl)Ni(μ-Cl)}2 (12145-60-7)

Guidance literature:

at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/om4002632

Reference yield: 80.0%

[Ni(η3-CH2CMeCH2)Cl]2 (12145-60-7) + potassium N-(2,6-diisopropylphenyl)-2-(2,6-diisopropylphenylimino)-1-methylenepropylamide (436808-40-1) → ((CH(CH3)2)2C6H3NC)2CH3CH2Ni(CH2CCH3CH2) (436808-47-8)

Guidance literature:

In not given; ligand was added to Ni-complex;

DOI:10.1021/om020251b

Reference yield: 63.0%

N-phenyl-2-cyano-N-2,6-diisopropylphenyl-β-diketiminate + [(C4H7)NiCl]2 (12145-60-7) → [4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-2N,N’](η3-methallyl) nickel (II) (1501943-20-9)

Guidance literature:

N-phenyl-2-cyano-N-2,6-diisopropylphenyl-β-diketiminate; With potassium hydride; In diethyl ether; for 12h;

[(C₄H₇)NiCl]2; In tetrahydrofuran; at 20 ℃; for 4h;

DOI:10.1021/om400847b

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

3-Chloro-2-methylpropene

Downstream raw materials:

((CH(CH₃)2)2C₆H₃NC)2CH₃CH₂Ni(CH₂CCH₃CH₂)

[4-2,6-diisopropylphenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel (II)

[4-4-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)

[2-cyanophenyl-amino-pent-3-en-2-ylidene-amino-benzonitrilate k-²N,N’](η³-methallyl) nickel(II)