(1-CHLORO-2-FORMYLVINYL)FERROCENE

Base Information

• Chemical Name: (1-CHLORO-2-FORMYLVINYL)FERROCENE
• CAS No.: 12085-68-6
• Molecular Formula: C13H11 Cl Fe O
• Molecular Weight: 274.53
• Mol file: 12085-68-6.mol

Synonyms:Iron,[(1-chloro-2-formylvinyl)cyclopentadienyl]cyclopentadienyl- (7CI,8CI);(1-Chloro-3-oxo-1-propenyl)ferrocene; 3-Chloro-3-ferrocenyl-2-propenal;3-Ferrocenyl-3-chloropropenal; b-Ferrocenyl-b-chloroacrolein

Chemical Property of (1-CHLORO-2-FORMYLVINYL)FERROCENE

Chemical Property:

• Melting Point: 74-78 °C(lit.)
• PSA: 17.07000
• LogP: 2.73230

Purity/Quality:

98%min ^*data from raw suppliers

(1-Chloro-2-formylvinyl)ferrocene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-CHLORO-2-FORMYLVINYL)FERROCENE

There total 7 articles about (1-CHLORO-2-FORMYLVINYL)FERROCENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

acetylferrocene (1271-55-2) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → (1-chloro-2-formylvinyl)ferrocene (12085-68-6)

Guidance literature:

acetylferrocene; N,N-dimethyl-formamide; With trichlorophosphate; at 0 ℃; for 2.5h; Inert atmosphere;

With sodium acetate; In water; for 1h; Inert atmosphere;

DOI:10.15227/orgsyn.073.0262

Reference yield: 90.0%

acetylferrocene (1271-55-2) + N,N-dimethyl-formamide (68-12-2,33513-42-7) + trichlorophosphate (10025-87-3,12599-09-6,63736-95-8,39380-77-3) → (1-chloro-2-formylvinyl)ferrocene (12085-68-6)

Guidance literature:

N,N-dimethyl-formamide; trichlorophosphate; at 0 ℃; for 1h;

acetylferrocene; at 0 ℃; for 4h;

DOI:10.1039/c5ra17977g

Reference yield:

C10H9FeCClCHCHN(CH3)2(1+)*ClO4(1-)={C10H9FeCClCHCHN(CH3)2}ClO4 → (1-chloro-2-formylvinyl)ferrocene (12085-68-6)

Guidance literature:

With sodium carbonate; In water; acetone;

upstream raw materials:

(3-chloro-3-ferrocenylallylidene)dimethylammonium iodide

(3-chloro-3-ferrocenylallylidene)dimethylammonium perchlorate

(3-chloro-3-ferrocenylallylidene)dimethylammonium phenylsulphonate

acetylferrocene

Downstream raw materials:

Fe(C₁₀H₉C(NHC₆H₅)(CH)2(NHC₆H₅)(P(O)(OC₂H₅)2))

1-ferrocenyl-3-phenylamino-thiopropenone

3-ferrocenyl-1-phenyl-1H-pyrazole

5-ferrocenyl-1-phenyl-1H-pyrazole