1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

Base Information

Chemical Name:1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose
CAS No.:659721-26-3
Molecular Formula:C₃₉H₆₇O₈PSi₃
Molecular Weight:779.186
Hs Code.:

Synonyms:1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

Suppliers and Price of 1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

There total 2 articles about 1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 659721-21-8
(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

: [(1R,3R,4S,5S,6R)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-3-hydroxymethyl-2,7-dioxa-bicyclo[2.2.1]hept-1-ylmethyl]-phosphonic acid dibenzyl ester

: 659721-26-3
1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

Guidance literature:: With 4 A molecular sieve; camphor-10-sulfonic acid; In dichloromethane; for 17h; Heating;
DOI:10.1002/chem.200305141

Reference yield:

: 1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

: 659721-26-3
1,4-anhydro-1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-α-D-galactofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 77 percent / pyridine; (CF₃CO)2O / tetrahydrofuran / 3 h / 0 °C

2: 74 percent / camphorsulfonic acid; 4 Angstroem molecular sieves / CH₂Cl₂ / 17 h / Heating

With pyridine; 4 A molecular sieve; camphor-10-sulfonic acid; trifluoroacetic anhydride; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.200305141