(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

Base Information

Chemical Name:(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose
CAS No.:659721-21-8
Molecular Formula:C₃₉H₆₇O₈PSi₃
Molecular Weight:779.186
Hs Code.:

Synonyms:(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

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Chemical Property of (1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

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Technology Process of (1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

There total 4 articles about (1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 1-(dibenzyloxyphosphoryl)methyl-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

: 659721-21-8
(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

Guidance literature:: With pyridine; trifluoroacetic anhydride; In tetrahydrofuran; at 0 ℃; for 3h;
DOI:10.1002/chem.200305141

Reference yield: 77.0%

: 198420-74-5
2,3,6-tri-O-tert-butyldimethylsilyl-D-galactono-1,4-lactone

: C₁₅H₁₆LiO₃P

: 659721-21-8
(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

Guidance literature:: 2,3,6-tri-O-tert-butyldimethylsilyl-D-galactono-1,4-lactone; C₁₅H₁₆LiO₃P; In tetrahydrofuran;

With pyridine; trifluoroacetic anhydride; In tetrahydrofuran;
DOI:10.1016/j.tet.2006.12.028

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 659721-21-8
(1(1')Z)-1-(dibenzyloxyphosphoryl)methylidene-2,3,6-tri-O-tert-butyldimethylsilyl-D-galactofuranose

Guidance literature:: Multi-step reaction with 2 steps

1.1: 97 percent / imidazole / dimethylformamide

2.1: tetrahydrofuran

2.2: 77 percent / pyridine; trifluoroacetic anhydride / tetrahydrofuran

With 1H-imidazole; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2006.12.028