TETRABUTYLAMMONIUM METHANESULFONATE

Base Information

• Chemical Name: TETRABUTYLAMMONIUM METHANESULFONATE
• CAS No.: 65411-49-6
• Molecular Formula: C17H39NO3S
• Molecular Weight: 337.568
• Hs Code.: 2923900090
• European Community (EC) Number: 265-751-0
• DSSTox Substance ID: DTXSID30984026
• ChEMBL ID: CHEMBL1078326
• Mol file: 65411-49-6.mol

Synonyms:methanesulfonate; tetrabutylazanium;

Chemical Property of TETRABUTYLAMMONIUM METHANESULFONATE

Chemical Property:

• Melting Point: 78-80 °C
• PSA: 65.58000
• LogP: 5.24580
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 12
• Exact Mass: 337.26506528
• Heavy Atom Count: 22
• Complexity: 195

Purity/Quality:

99% ^*data from raw suppliers

Tetrabutylammonium methanesulfonate ≥97.0% (T) ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.CS(=O)(=O)[O-]

Technology Process of TETRABUTYLAMMONIUM METHANESULFONATE

There total 3 articles about TETRABUTYLAMMONIUM METHANESULFONATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dimethylsulfite (616-42-2) + tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium methanesulfonate (65411-49-6)

Guidance literature:

at 110 - 115 ℃; for 96h; under 750.075 - 1125.11 Torr; Product distribution / selectivity;

Reference yield: 100.0%

dimethylsulfite (616-42-2) + tetrabutylammonium acetate (10534-59-5) → tetrabutylammonium methanesulfonate (65411-49-6)

Guidance literature:

at 120 ℃; for 28h; Product distribution / selectivity;

Reference yield: 90.0%

methanesulfonic acid (75-75-2,98527-29-8) + tetrabutylammomium bromide (1643-19-2) → tetrabutylammonium methanesulfonate (65411-49-6)

Guidance literature:

With trimethyl phosphite; at 0 - 60 ℃; for 15h; Inert atmosphere; neat (no solvent);

DOI:10.1002/ejoc.201200370

upstream raw materials:

dimethylsulfite

tetrabutylammonium acetate

tetrabutylammomium bromide

methanesulfonic acid

Downstream raw materials:

1,2-dichloro-heptane

Methanesulfonic acid 1-chloromethyl-hexyl ester

2-chloroethyl mesylate

1,2-dichloro-ethane

Refernces

• 1、 -. "Process for the Preparation of Onium Alkylsulfonates". Page/Page column 10-11. . Retrieved 2008/12/08.