COPPER PHOSPHIDE

Base Information

• Chemical Name: COPPER PHOSPHIDE
• CAS No.: 12019-57-7
• Molecular Formula: Cu₃P
• Molecular Weight: 221.612
• Mol file: 12019-57-7.mol

Synonyms:COPPER(I)PHOSPHIDE;;tricopper phosphide;;Cupric phosphide,lump,cu3p;;Phosphinidynetricopper(I);;CUPROUS PHOSPHIDE;;CUPRIC PHOSPHIDE;;

Chemical Property of COPPER PHOSPHIDE

Chemical Property:

• Melting Point: decomposes [CRC10]
• PSA: 13.59000
• Density: 6.600
• LogP: 0.85370
• Water Solubility.: insoluble H2O [CRC10]

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Manufacturing phosphor-bronze.

Technology Process of COPPER PHOSPHIDE

There total 14 articles about COPPER PHOSPHIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

copper(ll) sulfate pentahydrate + phosphorous → copper phosphide (12019-57-7)

Guidance literature:

In ethanol; water; ethylene glycol; byproducts: PH3, C2H4; High Pressure; stirring of CuSO4*5H2O, glycol, H2O and EtOH; transferring in Teflon lined autoclave; addn. of yellow P, sealing; heating from room temp. to 180°C; heating at this temp. for 12 h; cooling to room temp., dispersing of ppt. in benzene by stirring; filtration, washing with EtOH and H2O; drying in vac. at 50°C for 4 h;

DOI:10.1016/j.ssc.2008.12.046

Reference yield: 56.0%

phosphorous + copper (12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8) → copper phosphide (12019-57-7)

Guidance literature:

In neat (no solvent, solid phase); metal and phosphor (1:2 ratio) were mixed, then mixt. was heated to 700°C at rate 20°C/min in flowing N2, reaction was maintained for 0.5 h at 700°C, then cooled to room temp., finally phosphide was passivated in flow 1vol%O2/N2; XRD;

DOI:10.1016/j.jssc.2011.03.057

Reference yield:

copper(I) chloride * PH3 + water (7732-18-5) → copper phosphide (12019-57-7) + phosphan (7803-51-2)

Guidance literature:

In water; decompn. with cold H2O;;

upstream raw materials:

copper

copper(I) sulfide

phosphorus

water

Downstream raw materials:

copper phosphide

Refernces

• 1、 Ann Aitken, Jennifer,Ganzha-Hazen, Valentina,Brock, Stephanie L.. "Solvothermal syntheses of Cu3P via reactions of amorphous red phosphorus with a variety of copper sources". . p. 970 - 975. Retrieved 2005.
• 2、 Vineesh, Thaze Veetil,Yarmiayev, Valeria,Zitoun, David. "Tailoring the electrochemical hydrogen evolution activity of Cu3P through oxophilic surface modification". . . Retrieved 2020.
• 3、 Song, Limin,Zhang, Shujuan,Wei, Qingwu. "An approach to preparing porous and hollow metal phosphides with higher hydrodesulfurization activity". . p. 1556 - 1560. Retrieved 2011.
• 4、 Rosenstein, L.. "". . p. 883 - 883. Retrieved 1920.
• 5、 Mauvernay,Doublet,Monconduit. "Redox mechanism in the binary transition metal phosphide Cu3P". . p. 1252 - 1257. Retrieved 2006.
• 6、 Woo, Katherine E.,Wang, Jian,Mark, Justin,Kovnir, Kirill. "Directing Boron-Phosphorus Bonds in Crystalline Solid: Oxidative Polymerization of P═B═P Monomers into 1D Chains". . p. 13017 - 13021. Retrieved 2019.
• 7、 Guo, Qing,Huang, Limin,Li, Xu-Bing,Liang, Fei,Sun, Zongzhao,Wang, Yang,Wu, Li-Zhu,Xia, Shu-Guang,Zhang, Z. Conrad. "Optimal d-band-induced Cu3N as a cocatalyst on metal sulfides for boosting photocatalytic hydrogen evolution". . p. 22601 - 22606. Retrieved 2020.
• 8、 Bird, R. M.,Diggs, S. H.. "". . p. 1382 - 1392. Retrieved 1914.