2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol

Base Information

• Chemical Name: 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol
• CAS No.: 132868-64-5
• Molecular Formula: C₁₆H₁₅F₁₃OSi
• Molecular Weight: 498.359
• Mol file: 132868-64-5.mol

Synonyms:2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol

Chemical Property of 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol

There total 1 articles about 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-perfluorohexyl iodide (355-43-1) + benzoyltrimethylsilane (5908-41-8) → 2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol (132868-64-5)

Guidance literature:

With ethylmagnesium bromide; In diethyl ether; at -45 ℃; Mechanism; further reaction with MeLi/LiBr;

DOI:10.1016/S0040-4039(00)71224-X

Reference yield: 92.0%

2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol (132868-64-5) + 1,2-diamino-benzene (95-54-5) → 3-fluoro-2-(perfluorobutyl)-4-phenylbenzo-1,5-diazepine

Guidance literature:

With magnesium sulfate; In diethyl ether; for 24h; Heating;

DOI:10.1002/ejoc.200300671

Reference yield: 88.0%

2,2,3,3,4,4,5,5,6,6,7,7,7-Tridecafluoro-1-phenyl-1-trimethylsilanyl-heptan-1-ol (132868-64-5) + ethylenediamine (107-15-3,85404-18-8) → 2-(1'-fluoro-2'-oxo-2'-phenylethyl)-2-perfluorobutylimidazolidine

Guidance literature:

In diethyl ether; for 4h; Heating;

DOI:10.1002/ejoc.200300671

upstream raw materials:

n-perfluorohexyl iodide

benzoyltrimethylsilane

Downstream raw materials:

(E)-Perfluorohex-1-enyl phenyl ketone