PLATINUM RHODIUM

Base Information

• Chemical Name: PLATINUM RHODIUM
• CAS No.: 11107-71-4
• Molecular Formula: PtRh
• Molecular Weight: 297.986
• DSSTox Substance ID: DTXSID40580538
• Mol file: 11107-71-4.mol

Synonyms:PLATINUM RHODIUM;PLATINUM RHODIUM ALLOY;PLATINUM/PLATINUM RHODIUM;platinum/10% rhodium alloy;platinum/13% rhodium alloy;platinum/30% rhodium alloy;platinum/6% rhodium alloy;PLATINUM/13% RHODIUM ALLOY, WIRE, 0.51MM DIAM., THERMOCOUPLE GRADE

Chemical Property of PLATINUM RHODIUM

Chemical Property:

• PSA: 0.00000
• LogP: -0.00250
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 297.87029
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

98%,99%, ^*data from raw suppliers

Platinum-rhodium alloy Rhodium 30% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Rh].[Pt]
• Uses: Platinum Rhodium foil, 0.025mm (0.001in) thick, 99.9% (metals basis) is used as a standard for calibration of base metal thermocouples. It is also used in the glass industry for furnace linings and complex fabrications.

Technology Process of PLATINUM RHODIUM

There total 6 articles about PLATINUM RHODIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

platinum(II) bis(acetylacetonate) + di(rhodium)tetracarbonyl dichloride → platinum-rhodium (11107-71-4)

Guidance literature:

In ethylene glycol; (N2, Schlenk) Pt- and Rh-complexes were dissolved in ethylene glycol along with PVP(55000) stabilizer, the temp. was ramped to a boil in less than 10 min, the suspn. was refluxed for about 2 h; quenched over ice;

DOI:10.1021/ja8061425

Reference yield:

rhodium(III) chloride trihydrate + dihydrogen hexachloroplatinate(IV) hexahydrate → platinum-rhodium (11107-71-4)

Guidance literature:

With HCl; In hydrogenchloride; Electrochem. Process; electroplated potentiostatically (-0.12 V vs. Ag/AgCl) from 0.160+/-0.001 g/l Pt + 0.160+/-0.001 Rh g/l soln. in 0.1 M HCl;

DOI:10.1016/j.electacta.2010.04.040

Reference yield:

Rh(III) chloropentammine*PdCl4(2-) complex (281207-59-8) → platinum-rhodium (11107-71-4)

Guidance literature:

With H₂; In neat (no solvent); heating of the salt under a stream of hydrogen at 400°C; heating under a stream of helium at 600°C for 15 min;

DOI:10.1023/A:1015045310216

upstream raw materials:

Rh(III) chloropentammine*PdCl₄^(2-) complex

tetrachloroplatinato(II)chloropentaamminerhodium(III)

hydrogen

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